New macrocyclic ligands. XIV: Synthesis and X-ray structures of potentially pentadentate ligands incorporating non-symmetrically arranged N4S-, N3OS-, N2O2S- and N2S2O-heteroatoms

Darren S. Baldwin; Bruce F. Bowden; Paul A. Duckworth; Leonard F. Lindoy; Brian J. McCool; George V. Meehan; Ioana M. Vasilescu; S. Bruce Wild

doi:10.1071/CH02121

New macrocyclic ligands. XIV: Synthesis and X-ray structures of potentially pentadentate ligands incorporating non-symmetrically arranged N₄S-, N₃OS-, N₂O₂S- and N₂S₂O-heteroatoms

Darren S. Baldwin, Bruce F. Bowden, Paul A. Duckworth, Leonard F. Lindoy, Brian J. McCool, George V. Meehan, Ioana M. Vasilescu, S. Bruce Wild

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The synthesis and characterization of new mixed-donor macrocyclic ligands incorporating nitrogen, sulfur and/or oxygen heteroatoms are described. The new 17- or 18-membered macrocyclic rings contain unsymmetrical arrangements of their heteroatoms in contrast to related, previously reported rings in which the donor sets are arranged symmetrically. The X-ray structures of the 17-membered rings incorporating N₄O- and N₄S-donor sets are presented.

Original language	English
Pages (from-to)	597-603
Number of pages	7
Journal	Australian Journal of Chemistry
Volume	55
Issue number	9
DOIs	https://doi.org/10.1071/CH02121
Publication status	Published - 2002

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Baldwin, D. S., Bowden, B. F., Duckworth, P. A., Lindoy, L. F., McCool, B. J., Meehan, G. V., Vasilescu, I. M., & Wild, S. B. (2002). New macrocyclic ligands. XIV: Synthesis and X-ray structures of potentially pentadentate ligands incorporating non-symmetrically arranged N₄S-, N₃OS-, N₂O₂S- and N₂S₂O-heteroatoms. Australian Journal of Chemistry, 55(9), 597-603. https://doi.org/10.1071/CH02121

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title = "New macrocyclic ligands. XIV: Synthesis and X-ray structures of potentially pentadentate ligands incorporating non-symmetrically arranged N4S-, N3OS-, N2O2S- and N2S2O-heteroatoms",

abstract = "The synthesis and characterization of new mixed-donor macrocyclic ligands incorporating nitrogen, sulfur and/or oxygen heteroatoms are described. The new 17- or 18-membered macrocyclic rings contain unsymmetrical arrangements of their heteroatoms in contrast to related, previously reported rings in which the donor sets are arranged symmetrically. The X-ray structures of the 17-membered rings incorporating N4O- and N4S-donor sets are presented.",

author = "Baldwin, {Darren S.} and Bowden, {Bruce F.} and Duckworth, {Paul A.} and Lindoy, {Leonard F.} and McCool, {Brian J.} and Meehan, {George V.} and Vasilescu, {Ioana M.} and Wild, {S. Bruce}",

year = "2002",

doi = "10.1071/CH02121",

language = "English",

volume = "55",

pages = "597--603",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

publisher = "CSIRO",

number = "9",

}

Baldwin, DS, Bowden, BF, Duckworth, PA, Lindoy, LF, McCool, BJ, Meehan, GV, Vasilescu, IM & Wild, SB 2002, 'New macrocyclic ligands. XIV: Synthesis and X-ray structures of potentially pentadentate ligands incorporating non-symmetrically arranged N₄S-, N₃OS-, N₂O₂S- and N₂S₂O-heteroatoms', Australian Journal of Chemistry, vol. 55, no. 9, pp. 597-603. https://doi.org/10.1071/CH02121

New macrocyclic ligands. XIV: Synthesis and X-ray structures of potentially pentadentate ligands incorporating non-symmetrically arranged N₄S-, N₃OS-, N₂O₂S- and N₂S₂O-heteroatoms. / Baldwin, Darren S.; Bowden, Bruce F.; Duckworth, Paul A. et al.
In: Australian Journal of Chemistry, Vol. 55, No. 9, 2002, p. 597-603.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - New macrocyclic ligands. XIV

T2 - Synthesis and X-ray structures of potentially pentadentate ligands incorporating non-symmetrically arranged N4S-, N3OS-, N2O2S- and N2S2O-heteroatoms

AU - Baldwin, Darren S.

AU - Bowden, Bruce F.

AU - Duckworth, Paul A.

AU - Lindoy, Leonard F.

AU - McCool, Brian J.

AU - Meehan, George V.

AU - Vasilescu, Ioana M.

AU - Wild, S. Bruce

PY - 2002

Y1 - 2002

N2 - The synthesis and characterization of new mixed-donor macrocyclic ligands incorporating nitrogen, sulfur and/or oxygen heteroatoms are described. The new 17- or 18-membered macrocyclic rings contain unsymmetrical arrangements of their heteroatoms in contrast to related, previously reported rings in which the donor sets are arranged symmetrically. The X-ray structures of the 17-membered rings incorporating N4O- and N4S-donor sets are presented.

AB - The synthesis and characterization of new mixed-donor macrocyclic ligands incorporating nitrogen, sulfur and/or oxygen heteroatoms are described. The new 17- or 18-membered macrocyclic rings contain unsymmetrical arrangements of their heteroatoms in contrast to related, previously reported rings in which the donor sets are arranged symmetrically. The X-ray structures of the 17-membered rings incorporating N4O- and N4S-donor sets are presented.

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U2 - 10.1071/CH02121

DO - 10.1071/CH02121

M3 - Article

SN - 0004-9425

VL - 55

SP - 597

EP - 603

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 9

ER -

New macrocyclic ligands. XIV: Synthesis and X-ray structures of potentially pentadentate ligands incorporating non-symmetrically arranged N₄S-, N₃OS-, N₂O₂S- and N₂S₂O-heteroatoms

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