New organometallic materials for nonlinear optics: metal 〈sigma〉-arylacetylides

Stephan Houbrechts; Koen J. Clays; Andre P. Persoons; Victorio Cadierno; M. P. Gamasa; Jose Gimeno; Ian R. Whittall; Mark G. Humphrey

New organometallic materials for nonlinear optics: metal 〈sigma〉-arylacetylides

Stephan Houbrechts^*, Koen J. Clays, Andre P. Persoons, Victorio Cadierno, M. P. Gamasa, Jose Gimeno, Ian R. Whittall, Mark G. Humphrey

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

25 Citations (Scopus)

Abstract

Hyper-Rayleigh scattering is used to investigate the nonlinear optical properties of novel organometallic compounds. For a series of ruthenium and gold σ- arylacetylides, including some bimetallic complexes, the influence of the organometallic donor group, chain length and type of acceptor on the quadratic hyperpolarizability is studied. The hyperpolarizabilities found are among the highest (10 ^-27 esu) known for organometallic compounds. Moreover, electric-field induced second-harmonic generation confirms these values and indicates that only one major tensor component is present.

Original language	English
Title of host publication	Proceedings of SPIE - The International Society for Optical Engineering
Editors	Gustaaf R. Moehlmann
Pages	98-108
Number of pages	11
Publication status	Published - 1996
Externally published	Yes
Event	Nonlinear Optical Properties of Organic Materials IX - Denver, CO, USA Duration: 7 Aug 1996 → 9 Aug 1996

Publication series

Name	Proceedings of SPIE - The International Society for Optical Engineering
Volume	2852
ISSN (Print)	0277-786X

Conference

Conference	Nonlinear Optical Properties of Organic Materials IX
City	Denver, CO, USA
Period	7/08/96 → 9/08/96

Cite this

Houbrechts, S., Clays, K. J., Persoons, A. P., Cadierno, V., Gamasa, M. P., Gimeno, J., Whittall, I. R., & Humphrey, M. G. (1996). New organometallic materials for nonlinear optics: metal 〈sigma〉-arylacetylides. In G. R. Moehlmann (Ed.), Proceedings of SPIE - The International Society for Optical Engineering (pp. 98-108). (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 2852).

@inproceedings{3128f634b64f48a88b6191bd04c77727,

title = "New organometallic materials for nonlinear optics: metal 〈sigma〉-arylacetylides",

abstract = "Hyper-Rayleigh scattering is used to investigate the nonlinear optical properties of novel organometallic compounds. For a series of ruthenium and gold σ- arylacetylides, including some bimetallic complexes, the influence of the organometallic donor group, chain length and type of acceptor on the quadratic hyperpolarizability is studied. The hyperpolarizabilities found are among the highest (10 -27 esu) known for organometallic compounds. Moreover, electric-field induced second-harmonic generation confirms these values and indicates that only one major tensor component is present.",

author = "Stephan Houbrechts and Clays, {Koen J.} and Persoons, {Andre P.} and Victorio Cadierno and Gamasa, {M. P.} and Jose Gimeno and Whittall, {Ian R.} and Humphrey, {Mark G.}",

year = "1996",

language = "English",

isbn = "0819422401",

series = "Proceedings of SPIE - The International Society for Optical Engineering",

pages = "98--108",

editor = "Moehlmann, {Gustaaf R.}",

booktitle = "Proceedings of SPIE - The International Society for Optical Engineering",

note = "Nonlinear Optical Properties of Organic Materials IX ; Conference date: 07-08-1996 Through 09-08-1996",

}

Houbrechts, S, Clays, KJ, Persoons, AP, Cadierno, V, Gamasa, MP, Gimeno, J, Whittall, IR & Humphrey, MG 1996, New organometallic materials for nonlinear optics: metal 〈sigma〉-arylacetylides. in GR Moehlmann (ed.), Proceedings of SPIE - The International Society for Optical Engineering. Proceedings of SPIE - The International Society for Optical Engineering, vol. 2852, pp. 98-108, Nonlinear Optical Properties of Organic Materials IX, Denver, CO, USA, 7/08/96.

New organometallic materials for nonlinear optics: metal 〈sigma〉-arylacetylides. / Houbrechts, Stephan; Clays, Koen J.; Persoons, Andre P. et al.
Proceedings of SPIE - The International Society for Optical Engineering. ed. / Gustaaf R. Moehlmann. 1996. p. 98-108 (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 2852).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - New organometallic materials for nonlinear optics

T2 - Nonlinear Optical Properties of Organic Materials IX

AU - Houbrechts, Stephan

AU - Clays, Koen J.

AU - Persoons, Andre P.

AU - Cadierno, Victorio

AU - Gamasa, M. P.

AU - Gimeno, Jose

AU - Whittall, Ian R.

AU - Humphrey, Mark G.

PY - 1996

Y1 - 1996

N2 - Hyper-Rayleigh scattering is used to investigate the nonlinear optical properties of novel organometallic compounds. For a series of ruthenium and gold σ- arylacetylides, including some bimetallic complexes, the influence of the organometallic donor group, chain length and type of acceptor on the quadratic hyperpolarizability is studied. The hyperpolarizabilities found are among the highest (10 -27 esu) known for organometallic compounds. Moreover, electric-field induced second-harmonic generation confirms these values and indicates that only one major tensor component is present.

AB - Hyper-Rayleigh scattering is used to investigate the nonlinear optical properties of novel organometallic compounds. For a series of ruthenium and gold σ- arylacetylides, including some bimetallic complexes, the influence of the organometallic donor group, chain length and type of acceptor on the quadratic hyperpolarizability is studied. The hyperpolarizabilities found are among the highest (10 -27 esu) known for organometallic compounds. Moreover, electric-field induced second-harmonic generation confirms these values and indicates that only one major tensor component is present.

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M3 - Conference contribution

AN - SCOPUS:0030379942

SN - 0819422401

SN - 9780819422408

T3 - Proceedings of SPIE - The International Society for Optical Engineering

SP - 98

EP - 108

BT - Proceedings of SPIE - The International Society for Optical Engineering

A2 - Moehlmann, Gustaaf R.

Y2 - 7 August 1996 through 9 August 1996

ER -

New organometallic materials for nonlinear optics: metal 〈sigma〉-arylacetylides

Abstract

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