Novel carbon monochalcogenide coordination mode: [Rh 2{μ- SeCMo(CO) 2(Tp*)} 2(η 4-cod) 2] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate; Cod = cyclo-octa-1,5-diene)

Anthony F. Hill; Caitlin M.A. McQueen

doi:10.1021/om3000086

Novel carbon monochalcogenide coordination mode: [Rh ₂{μ- SeCMo(CO) ₂(Tp)} ₂(η ⁴-cod) ₂] (Tp = hydrotris(3,5-dimethylpyrazol-1-yl)borate; Cod = cyclo-octa-1,5-diene)

Anthony F. Hill^*, Caitlin M.A. McQueen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The reaction of [Et ₄N][Mo(CSe)(CO) ₂(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with [Rh ₂(μ-Cl) ₂(η ⁴-cod) ₂] (cod = cyclo-octa-1,5-diene) results in the formation of the tetrametallic complex [Rh ₂{SeCMo(CO) ₂(Tp*)} ₂(η ⁴- cod) ₂] in which the CSe ligand adopts a crystallographically confirmed and unprecedented μ ₃:σ,σ′(Se), σ″(C) coordination mode.

Original language	English
Pages (from-to)	2482-2485
Number of pages	4
Journal	Organometallics
Volume	31
Issue number	6
DOIs	https://doi.org/10.1021/om3000086
Publication status	Published - 26 Mar 2012

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title = "Novel carbon monochalcogenide coordination mode: [Rh 2{μ- SeCMo(CO) 2(Tp*)} 2(η 4-cod) 2] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate; Cod = cyclo-octa-1,5-diene)",

abstract = "The reaction of [Et 4N][Mo(CSe)(CO) 2(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with [Rh 2(μ-Cl) 2(η 4-cod) 2] (cod = cyclo-octa-1,5-diene) results in the formation of the tetrametallic complex [Rh 2{SeCMo(CO) 2(Tp*)} 2(η 4- cod) 2] in which the CSe ligand adopts a crystallographically confirmed and unprecedented μ 3:σ,σ′(Se), σ″(C) coordination mode.",

author = "Hill, {Anthony F.} and McQueen, {Caitlin M.A.}",

year = "2012",

month = mar,

day = "26",

doi = "10.1021/om3000086",

language = "English",

volume = "31",

pages = "2482--2485",

journal = "Organometallics",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - Novel carbon monochalcogenide coordination mode

T2 - [Rh 2{μ- SeCMo(CO) 2(Tp*)} 2(η 4-cod) 2] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate; Cod = cyclo-octa-1,5-diene)

AU - Hill, Anthony F.

AU - McQueen, Caitlin M.A.

PY - 2012/3/26

Y1 - 2012/3/26

N2 - The reaction of [Et 4N][Mo(CSe)(CO) 2(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with [Rh 2(μ-Cl) 2(η 4-cod) 2] (cod = cyclo-octa-1,5-diene) results in the formation of the tetrametallic complex [Rh 2{SeCMo(CO) 2(Tp*)} 2(η 4- cod) 2] in which the CSe ligand adopts a crystallographically confirmed and unprecedented μ 3:σ,σ′(Se), σ″(C) coordination mode.

AB - The reaction of [Et 4N][Mo(CSe)(CO) 2(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with [Rh 2(μ-Cl) 2(η 4-cod) 2] (cod = cyclo-octa-1,5-diene) results in the formation of the tetrametallic complex [Rh 2{SeCMo(CO) 2(Tp*)} 2(η 4- cod) 2] in which the CSe ligand adopts a crystallographically confirmed and unprecedented μ 3:σ,σ′(Se), σ″(C) coordination mode.

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U2 - 10.1021/om3000086

DO - 10.1021/om3000086

M3 - Article

SN - 0276-7333

VL - 31

SP - 2482

EP - 2485

JO - Organometallics

JF - Organometallics

IS - 6

ER -

Novel carbon monochalcogenide coordination mode: [Rh ₂{μ- SeCMo(CO) ₂(Tp)} ₂(η ⁴-cod) ₂] (Tp = hydrotris(3,5-dimethylpyrazol-1-yl)borate; Cod = cyclo-octa-1,5-diene)

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