Novel heterobimetallic coordination of the H2B(mt)2 ligand: The complex [Mo(SnMe2Cl)(CO)3{μ-S: κ3-H,S,S′-H2B(mt)2}] (mt = methimazolyl)

Mark R.St J. Foreman; Anthony F. Hill; Matthew K. Smith; Never Tshabang

doi:10.1021/om050778z

Novel heterobimetallic coordination of the H₂B(mt)₂ ligand: The complex [Mo(SnMe₂Cl)(CO)₃{μ-S: κ³-H,S,S′-H₂B(mt)₂}] (mt = methimazolyl)

Mark R.St J. Foreman, Anthony F. Hill^*, Matthew K. Smith, Never Tshabang

^*Corresponding author for this work

Research School of Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Molybdenum stannyl complexes ligated by poly(methimazolyl)borate ligands are accessible via complementary strategies involving oxidative addition of either Ph₃Sn{HB(mt)₃} (mt = methimazolyl) or[Me ₂-Sn{H₂B(mt)₂}]Cl to molybdenum(0) precursors or alternatively via reactions of halostannanes with the salts Na[Mo(CO) ₃{H_xB(mt)_4-x}] (x = 1, 2). One example provides a novel complex in which the H₂B(mt)₂ ligand bridges both molybdenum and tin, thereby providing a model for an intermediate in the oxidative addition protocol.

Original language	English
Pages (from-to)	5224-5226
Number of pages	3
Journal	Organometallics
Volume	24
Issue number	22
DOIs	https://doi.org/10.1021/om050778z
Publication status	Published - 24 Oct 2005

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title = "Novel heterobimetallic coordination of the H2B(mt)2 ligand: The complex [Mo(SnMe2Cl)(CO)3\{μ-S: κ3-H,S,S′-H2B(mt)2\}] (mt = methimazolyl)",

abstract = "Molybdenum stannyl complexes ligated by poly(methimazolyl)borate ligands are accessible via complementary strategies involving oxidative addition of either Ph3Sn\{HB(mt)3\} (mt = methimazolyl) or[Me 2-Sn\{H2B(mt)2\}]Cl to molybdenum(0) precursors or alternatively via reactions of halostannanes with the salts Na[Mo(CO) 3\{HxB(mt)4-x\}] (x = 1, 2). One example provides a novel complex in which the H2B(mt)2 ligand bridges both molybdenum and tin, thereby providing a model for an intermediate in the oxidative addition protocol.",

author = "Foreman, \{Mark R.St J.\} and Hill, \{Anthony F.\} and Smith, \{Matthew K.\} and Never Tshabang",

year = "2005",

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doi = "10.1021/om050778z",

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T1 - Novel heterobimetallic coordination of the H2B(mt)2 ligand

T2 - The complex [Mo(SnMe2Cl)(CO)3{μ-S: κ3-H,S,S′-H2B(mt)2}] (mt = methimazolyl)

AU - Foreman, Mark R.St J.

AU - Hill, Anthony F.

AU - Smith, Matthew K.

AU - Tshabang, Never

PY - 2005/10/24

Y1 - 2005/10/24

N2 - Molybdenum stannyl complexes ligated by poly(methimazolyl)borate ligands are accessible via complementary strategies involving oxidative addition of either Ph3Sn{HB(mt)3} (mt = methimazolyl) or[Me 2-Sn{H2B(mt)2}]Cl to molybdenum(0) precursors or alternatively via reactions of halostannanes with the salts Na[Mo(CO) 3{HxB(mt)4-x}] (x = 1, 2). One example provides a novel complex in which the H2B(mt)2 ligand bridges both molybdenum and tin, thereby providing a model for an intermediate in the oxidative addition protocol.

AB - Molybdenum stannyl complexes ligated by poly(methimazolyl)borate ligands are accessible via complementary strategies involving oxidative addition of either Ph3Sn{HB(mt)3} (mt = methimazolyl) or[Me 2-Sn{H2B(mt)2}]Cl to molybdenum(0) precursors or alternatively via reactions of halostannanes with the salts Na[Mo(CO) 3{HxB(mt)4-x}] (x = 1, 2). One example provides a novel complex in which the H2B(mt)2 ligand bridges both molybdenum and tin, thereby providing a model for an intermediate in the oxidative addition protocol.

UR - https://www.scopus.com/pages/publications/27544432632

U2 - 10.1021/om050778z

DO - 10.1021/om050778z

M3 - Article

SN - 0276-7333

VL - 24

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EP - 5226

JO - Organometallics

JF - Organometallics

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ER -

Novel heterobimetallic coordination of the H₂B(mt)₂ ligand: The complex [Mo(SnMe₂Cl)(CO)₃{μ-S: κ³-H,S,S′-H₂B(mt)₂}] (mt = methimazolyl)

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