Novel poly(methimazolyl)borate complexes of niobium(V) and tantalum(V)

Anthony F. Hill; Matthew K. Smith

doi:10.1039/b415852k

Novel poly(methimazolyl)borate complexes of niobium(V) and tantalum(V)

Anthony F. Hill^*, Matthew K. Smith

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

The reactions of [MCl₄(η-C₅H₅)] (M = Nb, Ta) with Ph₃Sn{HB(mt)₃} (mt = methimazolyl) provide structurally characterised complexes of the new chlorobis(methimazolyl)-borate ligand, [MCl₃(η-C₅H₅){κ²- S.S′-HClB(mt)₂}].

Original language	English
Pages (from-to)	1920-1922
Number of pages	3
Journal	Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/b415852k
Publication status	Published - 14 Apr 2005

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title = "Novel poly(methimazolyl)borate complexes of niobium(V) and tantalum(V)",

abstract = "The reactions of [MCl4(η-C5H5)] (M = Nb, Ta) with Ph3Sn{HB(mt)3} (mt = methimazolyl) provide structurally characterised complexes of the new chlorobis(methimazolyl)-borate ligand, [MCl3(η-C5H5){κ2- S.S′-HClB(mt)2}].",

author = "Hill, {Anthony F.} and Smith, {Matthew K.}",

year = "2005",

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pages = "1920--1922",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Novel poly(methimazolyl)borate complexes of niobium(V) and tantalum(V)

AU - Hill, Anthony F.

AU - Smith, Matthew K.

PY - 2005/4/14

Y1 - 2005/4/14

N2 - The reactions of [MCl4(η-C5H5)] (M = Nb, Ta) with Ph3Sn{HB(mt)3} (mt = methimazolyl) provide structurally characterised complexes of the new chlorobis(methimazolyl)-borate ligand, [MCl3(η-C5H5){κ2- S.S′-HClB(mt)2}].

AB - The reactions of [MCl4(η-C5H5)] (M = Nb, Ta) with Ph3Sn{HB(mt)3} (mt = methimazolyl) provide structurally characterised complexes of the new chlorobis(methimazolyl)-borate ligand, [MCl3(η-C5H5){κ2- S.S′-HClB(mt)2}].

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U2 - 10.1039/b415852k

DO - 10.1039/b415852k

M3 - Article

SN - 1359-7345

SP - 1920

EP - 1922

JO - Chemical Communications

JF - Chemical Communications

IS - 14

ER -

Novel poly(methimazolyl)borate complexes of niobium(V) and tantalum(V)

Abstract

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