Novel syntheses of heterodinuclear phosphaalkenyl complexes: X-ray structure of [Ru{P(AuPPh3)=CHBut}Cl2(CO)(PPh 3)2]

Robin B. Bedford; Anthony F. Hill; Cameron Jones; Andrew J.P. White; David J. Williams; James D.E.T. Wilton-Ely

doi:10.1039/a606987h

Novel syntheses of heterodinuclear phosphaalkenyl complexes: X-ray structure of [Ru{P(AuPPh₃)=CHBu^t}Cl₂(CO)(PPh ₃)₂]

Robin B. Bedford, Anthony F. Hill^*, Cameron Jones, Andrew J.P. White, David J. Williams, James D.E.T. Wilton-Ely

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

The reaction of [Ru(P=CHBu^t)Cl(CE)(PPh₃)₂] (E = O, S) with [AuX(PPh₃)] (X = Cl, C≡CC₆H₄Me-4), HgCl₂ or Hg₂Cl₂ leads via addition of the Au-X or Hg-Cl bonds across the Ru-P linkage to the heterodinuclear phosphaalkene complexes [Ru{P(AuPPh₃)=CHBu^t}ClX(CE)(PPh₃)₂] and [Ru{P(HgCl)=CHBu^t}Cl₂(CE)(PPh₃)₂].

Original language	English
Pages (from-to)	179-180
Number of pages	2
Journal	Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/a606987h
Publication status	Published - 1997
Externally published	Yes

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title = "Novel syntheses of heterodinuclear phosphaalkenyl complexes: X-ray structure of [Ru{P(AuPPh3)=CHBut}Cl2(CO)(PPh 3)2]",

abstract = "The reaction of [Ru(P=CHBut)Cl(CE)(PPh3)2] (E = O, S) with [AuX(PPh3)] (X = Cl, C≡CC6H4Me-4), HgCl2 or Hg2Cl2 leads via addition of the Au-X or Hg-Cl bonds across the Ru-P linkage to the heterodinuclear phosphaalkene complexes [Ru{P(AuPPh3)=CHBut}ClX(CE)(PPh3)2] and [Ru{P(HgCl)=CHBut}Cl2(CE)(PPh3)2].",

author = "Bedford, {Robin B.} and Hill, {Anthony F.} and Cameron Jones and White, {Andrew J.P.} and Williams, {David J.} and Wilton-Ely, {James D.E.T.}",

year = "1997",

doi = "10.1039/a606987h",

language = "English",

pages = "179--180",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "2",

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TY - JOUR

T1 - Novel syntheses of heterodinuclear phosphaalkenyl complexes

T2 - X-ray structure of [Ru{P(AuPPh3)=CHBut}Cl2(CO)(PPh 3)2]

AU - Bedford, Robin B.

AU - Hill, Anthony F.

AU - Jones, Cameron

AU - White, Andrew J.P.

AU - Williams, David J.

AU - Wilton-Ely, James D.E.T.

PY - 1997

Y1 - 1997

N2 - The reaction of [Ru(P=CHBut)Cl(CE)(PPh3)2] (E = O, S) with [AuX(PPh3)] (X = Cl, C≡CC6H4Me-4), HgCl2 or Hg2Cl2 leads via addition of the Au-X or Hg-Cl bonds across the Ru-P linkage to the heterodinuclear phosphaalkene complexes [Ru{P(AuPPh3)=CHBut}ClX(CE)(PPh3)2] and [Ru{P(HgCl)=CHBut}Cl2(CE)(PPh3)2].

AB - The reaction of [Ru(P=CHBut)Cl(CE)(PPh3)2] (E = O, S) with [AuX(PPh3)] (X = Cl, C≡CC6H4Me-4), HgCl2 or Hg2Cl2 leads via addition of the Au-X or Hg-Cl bonds across the Ru-P linkage to the heterodinuclear phosphaalkene complexes [Ru{P(AuPPh3)=CHBut}ClX(CE)(PPh3)2] and [Ru{P(HgCl)=CHBut}Cl2(CE)(PPh3)2].

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U2 - 10.1039/a606987h

DO - 10.1039/a606987h

M3 - Article

AN - SCOPUS:0344109105

SN - 1359-7345

SP - 179

EP - 180

JO - Chemical Communications

JF - Chemical Communications

IS - 2

ER -

Novel syntheses of heterodinuclear phosphaalkenyl complexes: X-ray structure of [Ru{P(AuPPh₃)=CHBu^t}Cl₂(CO)(PPh ₃)₂]

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