On the nature of "RuCl(dmso)2{HB(mt)3}" (mt = methimazolyl)

Robyn J. Abernethy; Anthony F. Hill; Never Tshabang; Anthony C. Willis; Rowan D. Young

doi:10.1021/om8007426

On the nature of "RuCl(dmso)₂{HB(mt)₃}" (mt = methimazolyl)

Robyn J. Abernethy, Anthony F. Hill, Never Tshabang, Anthony C. Willis, Rowan D. Young

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The high-yield product of the reaction of [RuC1₂(dmso), ₄] (dmso = dimethylsulfoxide) with Na[HB(mt)₃] (mt = methimazolyl) is not, as reported, the complex [RuCl(dmso)2{? ³-S,S',S"-HB(mt)3}] but rather the isomeric [RuCl(dmso) ₂{?:³-H,S,S'-HB(mt)3}], which features a three-center, two-electron B-H-Ru interaction, as also found for the complex [RuH(PPh ₃)₂{k³-H,S,S-H₂^B(mt)2}], which results from [RuHCl(PPh₃)₃] and Na[H ₂B(mt)₂].

Original language	English
Pages (from-to)	488-492
Number of pages	5
Journal	Organometallics
Volume	28
Issue number	2
DOIs	https://doi.org/10.1021/om8007426
Publication status	Published - 26 Jan 2009

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title = "On the nature of {"}RuCl(dmso)2\{HB(mt)3\}{"} (mt = methimazolyl)",

abstract = "The high-yield product of the reaction of [RuC12(dmso), 4] (dmso = dimethylsulfoxide) with Na[HB(mt)3] (mt = methimazolyl) is not, as reported, the complex [RuCl(dmso)2\{? 3-S,S',S{"}-HB(mt)3\}] but rather the isomeric [RuCl(dmso) 2\{?:3-H,S,S'-HB(mt)3\}], which features a three-center, two-electron B-H-Ru interaction, as also found for the complex [RuH(PPh 3)2\{k3-H,S,S-H2B(mt)2\}], which results from [RuHCl(PPh3)3] and Na[H 2B(mt)2].",

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doi = "10.1021/om8007426",

language = "English",

volume = "28",

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journal = "Organometallics",

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T1 - On the nature of "RuCl(dmso)2{HB(mt)3}" (mt = methimazolyl)

AU - Abernethy, Robyn J.

AU - Hill, Anthony F.

AU - Tshabang, Never

AU - Willis, Anthony C.

AU - Young, Rowan D.

PY - 2009/1/26

Y1 - 2009/1/26

N2 - The high-yield product of the reaction of [RuC12(dmso), 4] (dmso = dimethylsulfoxide) with Na[HB(mt)3] (mt = methimazolyl) is not, as reported, the complex [RuCl(dmso)2{? 3-S,S',S"-HB(mt)3}] but rather the isomeric [RuCl(dmso) 2{?:3-H,S,S'-HB(mt)3}], which features a three-center, two-electron B-H-Ru interaction, as also found for the complex [RuH(PPh 3)2{k3-H,S,S-H2B(mt)2}], which results from [RuHCl(PPh3)3] and Na[H 2B(mt)2].

AB - The high-yield product of the reaction of [RuC12(dmso), 4] (dmso = dimethylsulfoxide) with Na[HB(mt)3] (mt = methimazolyl) is not, as reported, the complex [RuCl(dmso)2{? 3-S,S',S"-HB(mt)3}] but rather the isomeric [RuCl(dmso) 2{?:3-H,S,S'-HB(mt)3}], which features a three-center, two-electron B-H-Ru interaction, as also found for the complex [RuH(PPh 3)2{k3-H,S,S-H2B(mt)2}], which results from [RuHCl(PPh3)3] and Na[H 2B(mt)2].

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U2 - 10.1021/om8007426

DO - 10.1021/om8007426

M3 - Article

SN - 0276-7333

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JO - Organometallics

JF - Organometallics

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ER -

On the nature of "RuCl(dmso)2{HB(mt)3}" (mt = methimazolyl)

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On the nature of "RuCl(dmso)₂{HB(mt)₃}" (mt = methimazolyl)