On the Reactions of [rucl2(pph3)3] with Thia Crown Ethers - Molecular-structures of [rucl2(pph3)([9]anes3)] ([9]anes3 = 1,4,7-trithiacyclononane) and [rucl(pph3)([14]anes4)clo4 ([14]anes4 = 1,4,8,11-tetrathiacyclotetradecane): Molecular structures of [RuCl2(PPh3)([9]aneS3)] ([9]aneS3 = 1,4,7-trithiacyclononane) and [RuCl(PPh3)([14]aneS4)]ClO4 ([14]aneS4 = 1,4,8,11-tetrathiacyclotetradecane)

Nathaniel W. Alcock; Jason C. Cannadine; George R. Clark; Anthony F. Hill

doi:10.1039/DT9930001131

On the Reactions of [rucl2(pph3)3] with Thia Crown Ethers - Molecular-structures of [rucl2(pph3)([9]anes3)] ([9]anes3 = 1,4,7-trithiacyclononane) and [rucl(pph3)([14]anes4)clo4 ([14]anes4 = 1,4,8,11-tetrathiacyclotetradecane): Molecular structures of [RuCl₂(PPh₃)([9]aneS₃)] ([9]aneS₃ = 1,4,7-trithiacyclononane) and [RuCl(PPh₃)([14]aneS₄)]ClO₄ ([14]aneS₄ = 1,4,8,11-tetrathiacyclotetradecane)

Nathaniel W. Alcock, Jason C. Cannadine, George R. Clark, Anthony F. Hill^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

The reaction of [RuCl₂(PPh₃)₃] with 1,4,7-trithiacyclononane ([9]aneS₃) gives the neutral complex [RuCl₂(PPh₃)([9]aneS₃)] while the same complex with 1,4,8,11-tetrathiacyclotetradecane ([14]aneS₄) followed by chloride-perchlorate metathesis provides the salt cis-[RuCl(PPh₃)([14]aneS₄)]ClO₄. The structures of both complexes have been determined by X-ray crystallography.

Original language	English
Pages (from-to)	1131-1135
Number of pages	5
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	7
DOIs	https://doi.org/10.1039/DT9930001131 https://doi.org/10.1039/dt9930001131
Publication status	Published - 1993
Externally published	Yes

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Alcock, N. W., Cannadine, J. C., Clark, G. R., & Hill, A. F. (1993). On the Reactions of [rucl2(pph3)3] with Thia Crown Ethers - Molecular-structures of [rucl2(pph3)([9]anes3)] ([9]anes3 = 1,4,7-trithiacyclononane) and [rucl(pph3)([14]anes4)clo4 ([14]anes4 = 1,4,8,11-tetrathiacyclotetradecane): Molecular structures of [RuCl₂(PPh₃)([9]aneS₃)] ([9]aneS₃ = 1,4,7-trithiacyclononane) and [RuCl(PPh₃)([14]aneS₄)]ClO₄ ([14]aneS₄ = 1,4,8,11-tetrathiacyclotetradecane). Journal of the Chemical Society, Dalton Transactions, (7), 1131-1135. https://doi.org/10.1039/DT9930001131, https://doi.org/10.1039/dt9930001131

Alcock, Nathaniel W. ; Cannadine, Jason C. ; Clark, George R. et al. / On the Reactions of [rucl2(pph3)3] with Thia Crown Ethers - Molecular-structures of [rucl2(pph3)([9]anes3)] ([9]anes3 = 1,4,7-trithiacyclononane) and [rucl(pph3)([14]anes4)clo4 ([14]anes4 = 1,4,8,11-tetrathiacyclotetradecane) : Molecular structures of [RuCl₂(PPh₃)([9]aneS₃)] ([9]aneS₃ = 1,4,7-trithiacyclononane) and [RuCl(PPh₃)([14]aneS₄)]ClO₄ ([14]aneS₄ = 1,4,8,11-tetrathiacyclotetradecane). In: Journal of the Chemical Society, Dalton Transactions. 1993 ; No. 7. pp. 1131-1135.

@article{ce933c9b11cd44c48a9bdff4a285ee1e,

title = "On the Reactions of [rucl2(pph3)3] with Thia Crown Ethers - Molecular-structures of [rucl2(pph3)([9]anes3)] ([9]anes3 = 1,4,7-trithiacyclononane) and [rucl(pph3)([14]anes4)clo4 ([14]anes4 = 1,4,8,11-tetrathiacyclotetradecane): Molecular structures of [RuCl2(PPh3)([9]aneS3)] ([9]aneS3 = 1,4,7-trithiacyclononane) and [RuCl(PPh3)([14]aneS4)]ClO4 ([14]aneS4 = 1,4,8,11-tetrathiacyclotetradecane)",

abstract = "The reaction of [RuCl2(PPh3)3] with 1,4,7-trithiacyclononane ([9]aneS3) gives the neutral complex [RuCl2(PPh3)([9]aneS3)] while the same complex with 1,4,8,11-tetrathiacyclotetradecane ([14]aneS4) followed by chloride-perchlorate metathesis provides the salt cis-[RuCl(PPh3)([14]aneS4)]ClO4. The structures of both complexes have been determined by X-ray crystallography.",

keywords = "Complexes",

author = "Alcock, {Nathaniel W.} and Cannadine, {Jason C.} and Clark, {George R.} and Hill, {Anthony F.}",

year = "1993",

doi = "10.1039/DT9930001131",

language = "English",

pages = "1131--1135",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

number = "7",

}

Alcock, NW, Cannadine, JC, Clark, GR & Hill, AF 1993, 'On the Reactions of [rucl2(pph3)3] with Thia Crown Ethers - Molecular-structures of [rucl2(pph3)([9]anes3)] ([9]anes3 = 1,4,7-trithiacyclononane) and [rucl(pph3)([14]anes4)clo4 ([14]anes4 = 1,4,8,11-tetrathiacyclotetradecane): Molecular structures of [RuCl₂(PPh₃)([9]aneS₃)] ([9]aneS₃ = 1,4,7-trithiacyclononane) and [RuCl(PPh₃)([14]aneS₄)]ClO₄ ([14]aneS₄ = 1,4,8,11-tetrathiacyclotetradecane)', Journal of the Chemical Society, Dalton Transactions, no. 7, pp. 1131-1135. https://doi.org/10.1039/DT9930001131, https://doi.org/10.1039/dt9930001131

On the Reactions of [rucl2(pph3)3] with Thia Crown Ethers - Molecular-structures of [rucl2(pph3)([9]anes3)] ([9]anes3 = 1,4,7-trithiacyclononane) and [rucl(pph3)([14]anes4)clo4 ([14]anes4 = 1,4,8,11-tetrathiacyclotetradecane): Molecular structures of [RuCl₂(PPh₃)([9]aneS₃)] ([9]aneS₃ = 1,4,7-trithiacyclononane) and [RuCl(PPh₃)([14]aneS₄)]ClO₄ ([14]aneS₄ = 1,4,8,11-tetrathiacyclotetradecane). / Alcock, Nathaniel W.; Cannadine, Jason C.; Clark, George R. et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 7, 1993, p. 1131-1135.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - On the Reactions of [rucl2(pph3)3] with Thia Crown Ethers - Molecular-structures of [rucl2(pph3)([9]anes3)] ([9]anes3 = 1,4,7-trithiacyclononane) and [rucl(pph3)([14]anes4)clo4 ([14]anes4 = 1,4,8,11-tetrathiacyclotetradecane)

T2 - Molecular structures of [RuCl2(PPh3)([9]aneS3)] ([9]aneS3 = 1,4,7-trithiacyclononane) and [RuCl(PPh3)([14]aneS4)]ClO4 ([14]aneS4 = 1,4,8,11-tetrathiacyclotetradecane)

AU - Alcock, Nathaniel W.

AU - Cannadine, Jason C.

AU - Clark, George R.

AU - Hill, Anthony F.

PY - 1993

Y1 - 1993

N2 - The reaction of [RuCl2(PPh3)3] with 1,4,7-trithiacyclononane ([9]aneS3) gives the neutral complex [RuCl2(PPh3)([9]aneS3)] while the same complex with 1,4,8,11-tetrathiacyclotetradecane ([14]aneS4) followed by chloride-perchlorate metathesis provides the salt cis-[RuCl(PPh3)([14]aneS4)]ClO4. The structures of both complexes have been determined by X-ray crystallography.

AB - The reaction of [RuCl2(PPh3)3] with 1,4,7-trithiacyclononane ([9]aneS3) gives the neutral complex [RuCl2(PPh3)([9]aneS3)] while the same complex with 1,4,8,11-tetrathiacyclotetradecane ([14]aneS4) followed by chloride-perchlorate metathesis provides the salt cis-[RuCl(PPh3)([14]aneS4)]ClO4. The structures of both complexes have been determined by X-ray crystallography.

KW - Complexes

UR - http://www.scopus.com/inward/record.url?scp=37049083986&partnerID=8YFLogxK

U2 - 10.1039/DT9930001131

DO - 10.1039/DT9930001131

M3 - Article

AN - SCOPUS:37049083986

SN - 1472-7773

SP - 1131

EP - 1135

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 7

ER -

Alcock NW, Cannadine JC, Clark GR, Hill AF. On the Reactions of [rucl2(pph3)3] with Thia Crown Ethers - Molecular-structures of [rucl2(pph3)([9]anes3)] ([9]anes3 = 1,4,7-trithiacyclononane) and [rucl(pph3)([14]anes4)clo4 ([14]anes4 = 1,4,8,11-tetrathiacyclotetradecane): Molecular structures of [RuCl₂(PPh₃)([9]aneS₃)] ([9]aneS₃ = 1,4,7-trithiacyclononane) and [RuCl(PPh₃)([14]aneS₄)]ClO₄ ([14]aneS₄ = 1,4,8,11-tetrathiacyclotetradecane). Journal of the Chemical Society, Dalton Transactions. 1993;(7):1131-1135. doi: 10.1039/DT9930001131, 10.1039/dt9930001131

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