On the selective cleavage of nitrous oxide by metal-amide complexes

G. Cavigliasso; A. Criddle; H. S. Kim; R. Stranger; B. F. Yates

doi:10.1039/c3dt53062k

On the selective cleavage of nitrous oxide by metal-amide complexes

G. Cavigliasso, A. Criddle, H. S. Kim, R. Stranger^*, B. F. Yates

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Computational investigation of nitrous oxide cleavage by metal-amide systems has shown that a bimetallic mechanism is compatible with the remarkable experimental observation of selective N-N bond scission by a di-molybdenum system, and that the interplay between the bonding energetics of reactants and products can both provide an explanation for the observed cleavage selectivity and be utilized to modify and design chemical behaviour.

Original language	English
Pages (from-to)	4631-4634
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	12
DOIs	https://doi.org/10.1039/c3dt53062k
Publication status	Published - 28 Mar 2014

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title = "On the selective cleavage of nitrous oxide by metal-amide complexes",

abstract = "Computational investigation of nitrous oxide cleavage by metal-amide systems has shown that a bimetallic mechanism is compatible with the remarkable experimental observation of selective N-N bond scission by a di-molybdenum system, and that the interplay between the bonding energetics of reactants and products can both provide an explanation for the observed cleavage selectivity and be utilized to modify and design chemical behaviour.",

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AU - Cavigliasso, G.

AU - Criddle, A.

AU - Kim, H. S.

AU - Stranger, R.

AU - Yates, B. F.

PY - 2014/3/28

Y1 - 2014/3/28

N2 - Computational investigation of nitrous oxide cleavage by metal-amide systems has shown that a bimetallic mechanism is compatible with the remarkable experimental observation of selective N-N bond scission by a di-molybdenum system, and that the interplay between the bonding energetics of reactants and products can both provide an explanation for the observed cleavage selectivity and be utilized to modify and design chemical behaviour.

AB - Computational investigation of nitrous oxide cleavage by metal-amide systems has shown that a bimetallic mechanism is compatible with the remarkable experimental observation of selective N-N bond scission by a di-molybdenum system, and that the interplay between the bonding energetics of reactants and products can both provide an explanation for the observed cleavage selectivity and be utilized to modify and design chemical behaviour.

UR - https://www.scopus.com/pages/publications/84894802845

U2 - 10.1039/c3dt53062k

DO - 10.1039/c3dt53062k

M3 - Article

SN - 1477-9226

VL - 43

SP - 4631

EP - 4634

JO - Dalton Transactions

JF - Dalton Transactions

IS - 12

ER -

On the selective cleavage of nitrous oxide by metal-amide complexes

Abstract

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