One-step synthesis and exploratory chemistry of [5]dendralene

Gomotsang Bojase; Alan D. Payne; Anthony C. Willis; Michael S. Sherburn

doi:10.1002/anie.200704470

One-step synthesis and exploratory chemistry of [5]dendralene

Gomotsang Bojase, Alan D. Payne, Anthony C. Willis^*, Michael S. Sherburn

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

(Chemical Equation Presented) Complex polycycles made simple: A practical synthesis of the simplest cross-conjugated pentaene, [5]dendralene, is reported. The hydrocarbon undergoes controllable and atom-efficient domino sequences (see scheme) to generate complex polycyclic frameworks in an operationally simple manner.

Original language	English
Pages (from-to)	910-912
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	5
DOIs	https://doi.org/10.1002/anie.200704470
Publication status	Published - 2008

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abstract = "(Chemical Equation Presented) Complex polycycles made simple: A practical synthesis of the simplest cross-conjugated pentaene, [5]dendralene, is reported. The hydrocarbon undergoes controllable and atom-efficient domino sequences (see scheme) to generate complex polycyclic frameworks in an operationally simple manner.",

keywords = "Dendralene, Diels-Alder reactions, Domino reactions, Electrocyclic reactions, Hydrocarbons",

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AU - Bojase, Gomotsang

AU - Payne, Alan D.

AU - Willis, Anthony C.

AU - Sherburn, Michael S.

PY - 2008

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AB - (Chemical Equation Presented) Complex polycycles made simple: A practical synthesis of the simplest cross-conjugated pentaene, [5]dendralene, is reported. The hydrocarbon undergoes controllable and atom-efficient domino sequences (see scheme) to generate complex polycyclic frameworks in an operationally simple manner.

KW - Dendralene

KW - Diels-Alder reactions

KW - Domino reactions

KW - Electrocyclic reactions

KW - Hydrocarbons

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DO - 10.1002/anie.200704470

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JF - Angewandte Chemie - International Edition

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ER -

One-step synthesis and exploratory chemistry of [5]dendralene

Abstract

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