Organometallic complexes for non-linear optics VII 1. Cubic optical non-linearities of octahedral trans-bis{bis(diphenylphosphino) methane}ruthenium acetylide complexes; X-ray crystal structure of trans-[Ru( C≡CPh) ( 4-C≡CC6H4NO2) (dppm)2]

Andrew M. McDonagh; Marie P. Cifuentes; Ian R. Whittall; Mark G. Humphrey; Marek Samoc; Barry Luther-Davies; David C.R. Hockless

doi:10.1016/S0022-328X(96)06469-8

Organometallic complexes for non-linear optics VII ¹. Cubic optical non-linearities of octahedral trans-bis{bis(diphenylphosphino) methane}ruthenium acetylide complexes; X-ray crystal structure of trans-[Ru( C≡CPh) ( 4-C≡CC₆H₄NO₂) (dppm)₂]

Andrew M. McDonagh, Marie P. Cifuentes, Ian R. Whittall, Mark G. Humphrey^*, Marek Samoc, Barry Luther-Davies, David C.R. Hockless

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

Cubic molecular optical non-linearities of a systematically varied series of octahedral bis{bis(diphenylphosphino)methane}ruthenium σ-acetylide complexes have been determined by the Z-scan technique: the influence on the non-linear response of sequential replacement of chloro by acetylide ligand in trans-[RuCl₂(dppm)₂] and acetylide chain length in proceeding from 4-nitrophenyl-to 4-nitrobiphenyl-and 4-nitro-(E)-stilbenylacetylide has been studied. The first X-ray structural study of an unsymmetrical bis(acetylide) complex of this type, trans-[Ru(C≡CPh)(4-C≡CC₆H₄NO₂)(dppm)₂], is reported and confirms the trans-disposed stereochemistry of the alkynyl ligands.

Original language	English
Pages (from-to)	99-103
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	526
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(96)06469-8
Publication status	Published - 29 Nov 1996

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McDonagh, A. M., Cifuentes, M. P., Whittall, I. R., Humphrey, M. G., Samoc, M., Luther-Davies, B., & Hockless, D. C. R. (1996). Organometallic complexes for non-linear optics VII ¹. Cubic optical non-linearities of octahedral trans-bis{bis(diphenylphosphino) methane}ruthenium acetylide complexes; X-ray crystal structure of trans-[Ru( C≡CPh) ( 4-C≡CC₆H₄NO₂) (dppm)₂]. Journal of Organometallic Chemistry, 526(1), 99-103. https://doi.org/10.1016/S0022-328X(96)06469-8

McDonagh, Andrew M. ; Cifuentes, Marie P. ; Whittall, Ian R. et al. / Organometallic complexes for non-linear optics VII ¹. Cubic optical non-linearities of octahedral trans-bis{bis(diphenylphosphino) methane}ruthenium acetylide complexes; X-ray crystal structure of trans-[Ru( C≡CPh) ( 4-C≡CC₆H₄NO₂) (dppm)₂]. In: Journal of Organometallic Chemistry. 1996 ; Vol. 526, No. 1. pp. 99-103.

@article{a9ce28d32a994bf29b6cbb07e929f9e9,

title = "Organometallic complexes for non-linear optics VII 1. Cubic optical non-linearities of octahedral trans-bis{bis(diphenylphosphino) methane}ruthenium acetylide complexes; X-ray crystal structure of trans-[Ru( C≡CPh) ( 4-C≡CC6H4NO2) (dppm)2]",

abstract = "Cubic molecular optical non-linearities of a systematically varied series of octahedral bis{bis(diphenylphosphino)methane}ruthenium σ-acetylide complexes have been determined by the Z-scan technique: the influence on the non-linear response of sequential replacement of chloro by acetylide ligand in trans-[RuCl2(dppm)2] and acetylide chain length in proceeding from 4-nitrophenyl-to 4-nitrobiphenyl-and 4-nitro-(E)-stilbenylacetylide has been studied. The first X-ray structural study of an unsymmetrical bis(acetylide) complex of this type, trans-[Ru(C≡CPh)(4-C≡CC6H4NO2)(dppm)2], is reported and confirms the trans-disposed stereochemistry of the alkynyl ligands.",

keywords = "Acetylide, Alkynyl, Crystal structure, Cubic hyperpolarizabilities, Non-linear optics, Ruthenium",

author = "McDonagh, {Andrew M.} and Cifuentes, {Marie P.} and Whittall, {Ian R.} and Humphrey, {Mark G.} and Marek Samoc and Barry Luther-Davies and Hockless, {David C.R.}",

year = "1996",

month = nov,

day = "29",

doi = "10.1016/S0022-328X(96)06469-8",

language = "English",

volume = "526",

pages = "99--103",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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McDonagh, AM, Cifuentes, MP, Whittall, IR, Humphrey, MG, Samoc, M, Luther-Davies, B & Hockless, DCR 1996, 'Organometallic complexes for non-linear optics VII ¹. Cubic optical non-linearities of octahedral trans-bis{bis(diphenylphosphino) methane}ruthenium acetylide complexes; X-ray crystal structure of trans-[Ru( C≡CPh) ( 4-C≡CC₆H₄NO₂) (dppm)₂]', Journal of Organometallic Chemistry, vol. 526, no. 1, pp. 99-103. https://doi.org/10.1016/S0022-328X(96)06469-8

Organometallic complexes for non-linear optics VII ¹. Cubic optical non-linearities of octahedral trans-bis{bis(diphenylphosphino) methane}ruthenium acetylide complexes; X-ray crystal structure of trans-[Ru( C≡CPh) ( 4-C≡CC₆H₄NO₂) (dppm)₂]. / McDonagh, Andrew M.; Cifuentes, Marie P.; Whittall, Ian R. et al.
In: Journal of Organometallic Chemistry, Vol. 526, No. 1, 29.11.1996, p. 99-103.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Organometallic complexes for non-linear optics VII 1. Cubic optical non-linearities of octahedral trans-bis{bis(diphenylphosphino) methane}ruthenium acetylide complexes; X-ray crystal structure of trans-[Ru( C≡CPh) ( 4-C≡CC6H4NO2) (dppm)2]

AU - McDonagh, Andrew M.

AU - Cifuentes, Marie P.

AU - Whittall, Ian R.

AU - Humphrey, Mark G.

AU - Samoc, Marek

AU - Luther-Davies, Barry

AU - Hockless, David C.R.

PY - 1996/11/29

Y1 - 1996/11/29

N2 - Cubic molecular optical non-linearities of a systematically varied series of octahedral bis{bis(diphenylphosphino)methane}ruthenium σ-acetylide complexes have been determined by the Z-scan technique: the influence on the non-linear response of sequential replacement of chloro by acetylide ligand in trans-[RuCl2(dppm)2] and acetylide chain length in proceeding from 4-nitrophenyl-to 4-nitrobiphenyl-and 4-nitro-(E)-stilbenylacetylide has been studied. The first X-ray structural study of an unsymmetrical bis(acetylide) complex of this type, trans-[Ru(C≡CPh)(4-C≡CC6H4NO2)(dppm)2], is reported and confirms the trans-disposed stereochemistry of the alkynyl ligands.

AB - Cubic molecular optical non-linearities of a systematically varied series of octahedral bis{bis(diphenylphosphino)methane}ruthenium σ-acetylide complexes have been determined by the Z-scan technique: the influence on the non-linear response of sequential replacement of chloro by acetylide ligand in trans-[RuCl2(dppm)2] and acetylide chain length in proceeding from 4-nitrophenyl-to 4-nitrobiphenyl-and 4-nitro-(E)-stilbenylacetylide has been studied. The first X-ray structural study of an unsymmetrical bis(acetylide) complex of this type, trans-[Ru(C≡CPh)(4-C≡CC6H4NO2)(dppm)2], is reported and confirms the trans-disposed stereochemistry of the alkynyl ligands.

KW - Acetylide

KW - Alkynyl

KW - Crystal structure

KW - Cubic hyperpolarizabilities

KW - Non-linear optics

KW - Ruthenium

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U2 - 10.1016/S0022-328X(96)06469-8

DO - 10.1016/S0022-328X(96)06469-8

M3 - Article

AN - SCOPUS:0030606191

SN - 0022-328X

VL - 526

SP - 99

EP - 103

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

McDonagh AM, Cifuentes MP, Whittall IR, Humphrey MG, Samoc M, Luther-Davies B et al. Organometallic complexes for non-linear optics VII ¹. Cubic optical non-linearities of octahedral trans-bis{bis(diphenylphosphino) methane}ruthenium acetylide complexes; X-ray crystal structure of trans-[Ru( C≡CPh) ( 4-C≡CC₆H₄NO₂) (dppm)₂]. Journal of Organometallic Chemistry. 1996 Nov 29;526(1):99-103. doi: 10.1016/S0022-328X(96)06469-8