Organometallic complexes for nonlinear optics, 47 - Synthesis and cubic optical nonlinearity of a stilbenylethynylruthenium dendrimerab

Christopher J. Jeffery; Marie P. Cifuentes; Gulliver T. Dalton; T. Christopher Corkery; Michael D. Randles; Anthony C. Willis; Marek Samoc; Mark G. Humphrey

doi:10.1002/marc.200900859

Organometallic complexes for nonlinear optics, 47 - Synthesis and cubic optical nonlinearity of a stilbenylethynylruthenium dendrimer^ab

Christopher J. Jeffery, Marie P. Cifuentes, Gulliver T. Dalton, T. Christopher Corkery, Michael D. Randles, Anthony C. Willis, Marek Samoc^*, Mark G. Humphrey

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

(Figure Presented) The synthesis of the 1st generation dendrimer l,3,5-{trans-[Ru(C=C-3,5-(trans-[Ru(C= CPh)(dppe)₂(C=CC ₆H₄-4-(E)-CH=CH)] )₂C₆H ₃)(dppe)₂(C=CC₆H₄-4-(E)-CH=CH)] }₃C₆H₃ proceeds by a novel route that features Emmons-Horner-Wadsworth coupling of 1,3,5-C₆H₃(CH ₂PO(OEt)₂)₃ with trans-[Ru(C≡CC ₆H₄-4CHO)Cl(dppe)₂] and 1-I-C₆H ₃-3,5-(CH₂PO(OEt)₂)₂ with trans-[Ru(C≡CPh)(C≡CC₆H₄-4-CHO)(dppe) ₂] as key steps. The stilbenylethynylruthenium dendrimer is much more soluble than its ethynylated analog l,3,5-{trans-[Ru(C≡C-3,5-(trans- [Ru(C≡CPh) (dppe)₂(C≡CC₆H₄-4- C≡C)] )₂C₆H₃)(dppe)₂(C≡ CC₆H₄4-C≡C)] }₃C₆H₃ and, in contrast to the ethynylated analog, is a two-photon absorber at telecommunications wavelengths.

Original language	English
Pages (from-to)	846-849
Number of pages	4
Journal	Macromolecular Rapid Communications
Volume	31
Issue number	9-10
DOIs	https://doi.org/10.1002/marc.200900859
Publication status	Published - 12 May 2010

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@article{3727c71e1047439f8b7196e8ea14336e,

title = "Organometallic complexes for nonlinear optics, 47 - Synthesis and cubic optical nonlinearity of a stilbenylethynylruthenium dendrimerab",

abstract = "(Figure Presented) The synthesis of the 1st generation dendrimer l,3,5-\{trans-[Ru(C=C-3,5-(trans-[Ru(C= CPh)(dppe)2(C=CC 6H4-4-(E)-CH=CH)] )2C6H 3)(dppe)2(C=CC6H4-4-(E)-CH=CH)] \}3C6H3 proceeds by a novel route that features Emmons-Horner-Wadsworth coupling of 1,3,5-C6H3(CH 2PO(OEt)2)3 with trans-[Ru(C≡CC 6H4-4CHO)Cl(dppe)2] and 1-I-C6H 3-3,5-(CH2PO(OEt)2)2 with trans-[Ru(C≡CPh)(C≡CC6H4-4-CHO)(dppe) 2] as key steps. The stilbenylethynylruthenium dendrimer is much more soluble than its ethynylated analog l,3,5-\{trans-[Ru(C≡C-3,5-(trans- [Ru(C≡CPh) (dppe)2(C≡CC6H4-4- C≡C)] )2C6H3)(dppe)2(C≡ CC6H44-C≡C)] \}3C6H3 and, in contrast to the ethynylated analog, is a two-photon absorber at telecommunications wavelengths.",

keywords = "Crystal structure, Dendrimers, Inorganic materials, NLO, TEM",

author = "Jeffery, \{Christopher J.\} and Cifuentes, \{Marie P.\} and Dalton, \{Gulliver T.\} and Corkery, \{T. Christopher\} and Randles, \{Michael D.\} and Willis, \{Anthony C.\} and Marek Samoc and Humphrey, \{Mark G.\}",

year = "2010",

month = may,

day = "12",

doi = "10.1002/marc.200900859",

language = "English",

volume = "31",

pages = "846--849",

journal = "Macromolecular Rapid Communications",

issn = "1022-1336",

publisher = "Wiley-VCH Verlag GmbH",

number = "9-10",

}

TY - JOUR

T1 - Organometallic complexes for nonlinear optics, 47 - Synthesis and cubic optical nonlinearity of a stilbenylethynylruthenium dendrimerab

AU - Jeffery, Christopher J.

AU - Cifuentes, Marie P.

AU - Dalton, Gulliver T.

AU - Corkery, T. Christopher

AU - Randles, Michael D.

AU - Willis, Anthony C.

AU - Samoc, Marek

AU - Humphrey, Mark G.

PY - 2010/5/12

Y1 - 2010/5/12

N2 - (Figure Presented) The synthesis of the 1st generation dendrimer l,3,5-{trans-[Ru(C=C-3,5-(trans-[Ru(C= CPh)(dppe)2(C=CC 6H4-4-(E)-CH=CH)] )2C6H 3)(dppe)2(C=CC6H4-4-(E)-CH=CH)] }3C6H3 proceeds by a novel route that features Emmons-Horner-Wadsworth coupling of 1,3,5-C6H3(CH 2PO(OEt)2)3 with trans-[Ru(C≡CC 6H4-4CHO)Cl(dppe)2] and 1-I-C6H 3-3,5-(CH2PO(OEt)2)2 with trans-[Ru(C≡CPh)(C≡CC6H4-4-CHO)(dppe) 2] as key steps. The stilbenylethynylruthenium dendrimer is much more soluble than its ethynylated analog l,3,5-{trans-[Ru(C≡C-3,5-(trans- [Ru(C≡CPh) (dppe)2(C≡CC6H4-4- C≡C)] )2C6H3)(dppe)2(C≡ CC6H44-C≡C)] }3C6H3 and, in contrast to the ethynylated analog, is a two-photon absorber at telecommunications wavelengths.

AB - (Figure Presented) The synthesis of the 1st generation dendrimer l,3,5-{trans-[Ru(C=C-3,5-(trans-[Ru(C= CPh)(dppe)2(C=CC 6H4-4-(E)-CH=CH)] )2C6H 3)(dppe)2(C=CC6H4-4-(E)-CH=CH)] }3C6H3 proceeds by a novel route that features Emmons-Horner-Wadsworth coupling of 1,3,5-C6H3(CH 2PO(OEt)2)3 with trans-[Ru(C≡CC 6H4-4CHO)Cl(dppe)2] and 1-I-C6H 3-3,5-(CH2PO(OEt)2)2 with trans-[Ru(C≡CPh)(C≡CC6H4-4-CHO)(dppe) 2] as key steps. The stilbenylethynylruthenium dendrimer is much more soluble than its ethynylated analog l,3,5-{trans-[Ru(C≡C-3,5-(trans- [Ru(C≡CPh) (dppe)2(C≡CC6H4-4- C≡C)] )2C6H3)(dppe)2(C≡ CC6H44-C≡C)] }3C6H3 and, in contrast to the ethynylated analog, is a two-photon absorber at telecommunications wavelengths.

KW - Crystal structure

KW - Dendrimers

KW - Inorganic materials

KW - NLO

KW - TEM

UR - https://www.scopus.com/pages/publications/77952593997

U2 - 10.1002/marc.200900859

DO - 10.1002/marc.200900859

M3 - Article

SN - 1022-1336

VL - 31

SP - 846

EP - 849

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 9-10

ER -

Organometallic complexes for nonlinear optics, 47 - Synthesis and cubic optical nonlinearity of a stilbenylethynylruthenium dendrimer^ab

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