TY - JOUR
T1 - Organometallic Macrocycle Chemistry .1. the Reactions of [rucl2(pph3)3] with 1,4,7-trithiacyclononane and 1,4,8,11-tetrathiacyclotetradecane
AU - HILL, AF
AU - ALCOCK, NW
AU - CANNADINE, JC
AU - CLARK, GR
PY - 1992/3/17
Y1 - 1992/3/17
N2 - The reactions of [RuCl2(PPh3)3] with the thiacrown ethers 1,4,7-trithiacyclononane (9-S3) and 1,4,8,11-tetrathiacyclotetradecane (14-S4) provide the crystallographically characterised complexes [RuCl2(PPh3)(9-S3)] and cis-[RuCl(PPh3)(14-S4)]+. The thiocarbonyl containing salts [RuCl(CS) (PPh3)(9-S3)]ClO4 and [RuH(CS)(PPh3)(9-S3)]ClO4 are obtained by treatment of the complexes [RuCl2(OH2)(CS)(PPh3)2] and [RuClH(CS)(PPh3)3] with 9-S3.
AB - The reactions of [RuCl2(PPh3)3] with the thiacrown ethers 1,4,7-trithiacyclononane (9-S3) and 1,4,8,11-tetrathiacyclotetradecane (14-S4) provide the crystallographically characterised complexes [RuCl2(PPh3)(9-S3)] and cis-[RuCl(PPh3)(14-S4)]+. The thiocarbonyl containing salts [RuCl(CS) (PPh3)(9-S3)]ClO4 and [RuH(CS)(PPh3)(9-S3)]ClO4 are obtained by treatment of the complexes [RuCl2(OH2)(CS)(PPh3)2] and [RuClH(CS)(PPh3)3] with 9-S3.
KW - Complexes
UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:A1992HM83400014&DestLinkType=FullRecord&DestApp=WOS_CPL
U2 - 10.1016/0022-328X(92)83054-L
DO - 10.1016/0022-328X(92)83054-L
M3 - Short survey
SN - 0022-328X
VL - 426
SP - C40-C43
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 2
ER -