Organometallic Macrocycle Chemistry .1. the Reactions of [rucl2(pph3)3] with 1,4,7-trithiacyclononane and 1,4,8,11-tetrathiacyclotetradecane

AF HILL; NW ALCOCK; JC CANNADINE; GR CLARK

doi:10.1016/0022-328X(92)83054-L

Organometallic Macrocycle Chemistry .1. the Reactions of [rucl2(pph3)3] with 1,4,7-trithiacyclononane and 1,4,8,11-tetrathiacyclotetradecane

AF HILL
, NW ALCOCK
, JC CANNADINE
, GR CLARK

Research output: Contribution to journal › Short survey › peer-review

Abstract

The reactions of [RuCl2(PPh3)3] with the thiacrown ethers 1,4,7-trithiacyclononane (9-S3) and 1,4,8,11-tetrathiacyclotetradecane (14-S4) provide the crystallographically characterised complexes [RuCl2(PPh3)(9-S3)] and cis-[RuCl(PPh3)(14-S4)]+. The thiocarbonyl containing salts [RuCl(CS) (PPh3)(9-S3)]ClO4 and [RuH(CS)(PPh3)(9-S3)]ClO4 are obtained by treatment of the complexes [RuCl2(OH2)(CS)(PPh3)2] and [RuClH(CS)(PPh3)3] with 9-S3.

Original language	English
Pages (from-to)	C40-C43
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	426
Issue number	2
DOIs	https://doi.org/10.1016/0022-328X(92)83054-L
Publication status	Published - 17 Mar 1992
Externally published	Yes

Access to Document

10.1016/0022-328X(92)83054-L

Cite this

@article{7320a907d0e644c48d0b03337c20e690,

title = "Organometallic Macrocycle Chemistry .1. the Reactions of [rucl2(pph3)3] with 1,4,7-trithiacyclononane and 1,4,8,11-tetrathiacyclotetradecane",

abstract = "The reactions of [RuCl2(PPh3)3] with the thiacrown ethers 1,4,7-trithiacyclononane (9-S3) and 1,4,8,11-tetrathiacyclotetradecane (14-S4) provide the crystallographically characterised complexes [RuCl2(PPh3)(9-S3)] and cis-[RuCl(PPh3)(14-S4)]+. The thiocarbonyl containing salts [RuCl(CS) (PPh3)(9-S3)]ClO4 and [RuH(CS)(PPh3)(9-S3)]ClO4 are obtained by treatment of the complexes [RuCl2(OH2)(CS)(PPh3)2] and [RuClH(CS)(PPh3)3] with 9-S3.",

keywords = "Complexes",

author = "AF HILL and NW ALCOCK and JC CANNADINE and GR CLARK",

year = "1992",

month = mar,

day = "17",

doi = "10.1016/0022-328X(92)83054-L",

language = "English",

volume = "426",

pages = "C40--C43",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Organometallic Macrocycle Chemistry .1. the Reactions of [rucl2(pph3)3] with 1,4,7-trithiacyclononane and 1,4,8,11-tetrathiacyclotetradecane

AU - HILL, AF

AU - ALCOCK, NW

AU - CANNADINE, JC

AU - CLARK, GR

PY - 1992/3/17

Y1 - 1992/3/17

N2 - The reactions of [RuCl2(PPh3)3] with the thiacrown ethers 1,4,7-trithiacyclononane (9-S3) and 1,4,8,11-tetrathiacyclotetradecane (14-S4) provide the crystallographically characterised complexes [RuCl2(PPh3)(9-S3)] and cis-[RuCl(PPh3)(14-S4)]+. The thiocarbonyl containing salts [RuCl(CS) (PPh3)(9-S3)]ClO4 and [RuH(CS)(PPh3)(9-S3)]ClO4 are obtained by treatment of the complexes [RuCl2(OH2)(CS)(PPh3)2] and [RuClH(CS)(PPh3)3] with 9-S3.

AB - The reactions of [RuCl2(PPh3)3] with the thiacrown ethers 1,4,7-trithiacyclononane (9-S3) and 1,4,8,11-tetrathiacyclotetradecane (14-S4) provide the crystallographically characterised complexes [RuCl2(PPh3)(9-S3)] and cis-[RuCl(PPh3)(14-S4)]+. The thiocarbonyl containing salts [RuCl(CS) (PPh3)(9-S3)]ClO4 and [RuH(CS)(PPh3)(9-S3)]ClO4 are obtained by treatment of the complexes [RuCl2(OH2)(CS)(PPh3)2] and [RuClH(CS)(PPh3)3] with 9-S3.

KW - Complexes

UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:A1992HM83400014&DestLinkType=FullRecord&DestApp=WOS_CPL

U2 - 10.1016/0022-328X(92)83054-L

DO - 10.1016/0022-328X(92)83054-L

M3 - Short survey

SN - 0022-328X

VL - 426

SP - C40-C43

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Organometallic Macrocycle Chemistry .1. the Reactions of [rucl2(pph3)3] with 1,4,7-trithiacyclononane and 1,4,8,11-tetrathiacyclotetradecane

Abstract

Access to Document

Other files and links

Fingerprint

Cite this