Organometallic macrocycle chemistry. 5.1 σ-vinyl and σ-aryl complexes of ruthenium(II) ligated by 1,4,7-trithiacyclononane: X-ray crystal structure of [Ru(CH=CH2)(CO)(PPh3)([9]aneS 3)]PF6·2CH2Cl2

Jason C. Cannadine; Anthony F. Hill; Andrew J.P. White; David J. Williams; James D.E.T. Wilton-Ely

doi:10.1021/om960129a

Organometallic macrocycle chemistry. 5.¹ σ-vinyl and σ-aryl complexes of ruthenium(II) ligated by 1,4,7-trithiacyclononane: X-ray crystal structure of [Ru(CH=CH₂)(CO)(PPh₃)([9]aneS ₃)]PF6·2CH₂Cl₂

Jason C. Cannadine, Anthony F. Hill^*, Andrew J.P. White, David J. Williams, James D.E.T. Wilton-Ely

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The reaction of coordinatively unsaturated σ-vinyl complexes [Ru(CR=CHR′)Cl(CO)(PPh₃)₂] with 1,4,7-trithiacyclononane ([9]aneS₃) provides chiral salts of the "half-sandwich" complexes [Ru(CR=CHR′)(CO)(PPh₃)([9]aneS₃)]⁺. The synthesis of the σ-aryl complex [Ru(C₆H₄Me-4)(CO)(PPh₃)([9]aneS ₃)]⁺ is also described. A representative NMR study of one example allowed the assignment of individual chemical shifts for the 12 diastereotopic proton environments of the macrocycle. The crystal structure of [Ru(CH=CH₂)(CO)(PPh₃)-([9]aneS₃)]PF ₆·2CH₂Cl₂ is also reported.

Original language	English
Pages (from-to)	5409-5415
Number of pages	7
Journal	Organometallics
Volume	15
Issue number	25
DOIs	https://doi.org/10.1021/om960129a
Publication status	Published - 10 Dec 1996
Externally published	Yes

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@article{6a52559d0fea4ec5afa9e44154e04c2b,

title = "Organometallic macrocycle chemistry. 5.1 σ-vinyl and σ-aryl complexes of ruthenium(II) ligated by 1,4,7-trithiacyclononane: X-ray crystal structure of [Ru(CH=CH2)(CO)(PPh3)([9]aneS 3)]PF6·2CH2Cl2",

abstract = "The reaction of coordinatively unsaturated σ-vinyl complexes [Ru(CR=CHR′)Cl(CO)(PPh3)2] with 1,4,7-trithiacyclononane ([9]aneS3) provides chiral salts of the {"}half-sandwich{"} complexes [Ru(CR=CHR′)(CO)(PPh3)([9]aneS3)]+. The synthesis of the σ-aryl complex [Ru(C6H4Me-4)(CO)(PPh3)([9]aneS 3)]+ is also described. A representative NMR study of one example allowed the assignment of individual chemical shifts for the 12 diastereotopic proton environments of the macrocycle. The crystal structure of [Ru(CH=CH2)(CO)(PPh3)-([9]aneS3)]PF 6·2CH2Cl2 is also reported.",

author = "Cannadine, {Jason C.} and Hill, {Anthony F.} and White, {Andrew J.P.} and Williams, {David J.} and Wilton-Ely, {James D.E.T.}",

year = "1996",

month = dec,

day = "10",

doi = "10.1021/om960129a",

language = "English",

volume = "15",

pages = "5409--5415",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "25",

}

Organometallic macrocycle chemistry. 5.¹ σ-vinyl and σ-aryl complexes of ruthenium(II) ligated by 1,4,7-trithiacyclononane: X-ray crystal structure of [Ru(CH=CH₂)(CO)(PPh₃)([9]aneS ₃)]PF6·2CH₂Cl₂. / Cannadine, Jason C.; Hill, Anthony F.; White, Andrew J.P. et al.
In: Organometallics, Vol. 15, No. 25, 10.12.1996, p. 5409-5415.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Organometallic macrocycle chemistry. 5.1 σ-vinyl and σ-aryl complexes of ruthenium(II) ligated by 1,4,7-trithiacyclononane

T2 - X-ray crystal structure of [Ru(CH=CH2)(CO)(PPh3)([9]aneS 3)]PF6·2CH2Cl2

AU - Cannadine, Jason C.

AU - Hill, Anthony F.

AU - White, Andrew J.P.

AU - Williams, David J.

AU - Wilton-Ely, James D.E.T.

PY - 1996/12/10

Y1 - 1996/12/10

N2 - The reaction of coordinatively unsaturated σ-vinyl complexes [Ru(CR=CHR′)Cl(CO)(PPh3)2] with 1,4,7-trithiacyclononane ([9]aneS3) provides chiral salts of the "half-sandwich" complexes [Ru(CR=CHR′)(CO)(PPh3)([9]aneS3)]+. The synthesis of the σ-aryl complex [Ru(C6H4Me-4)(CO)(PPh3)([9]aneS 3)]+ is also described. A representative NMR study of one example allowed the assignment of individual chemical shifts for the 12 diastereotopic proton environments of the macrocycle. The crystal structure of [Ru(CH=CH2)(CO)(PPh3)-([9]aneS3)]PF 6·2CH2Cl2 is also reported.

AB - The reaction of coordinatively unsaturated σ-vinyl complexes [Ru(CR=CHR′)Cl(CO)(PPh3)2] with 1,4,7-trithiacyclononane ([9]aneS3) provides chiral salts of the "half-sandwich" complexes [Ru(CR=CHR′)(CO)(PPh3)([9]aneS3)]+. The synthesis of the σ-aryl complex [Ru(C6H4Me-4)(CO)(PPh3)([9]aneS 3)]+ is also described. A representative NMR study of one example allowed the assignment of individual chemical shifts for the 12 diastereotopic proton environments of the macrocycle. The crystal structure of [Ru(CH=CH2)(CO)(PPh3)-([9]aneS3)]PF 6·2CH2Cl2 is also reported.

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U2 - 10.1021/om960129a

DO - 10.1021/om960129a

M3 - Article

AN - SCOPUS:0009188679

SN - 0276-7333

VL - 15

SP - 5409

EP - 5415

JO - Organometallics

JF - Organometallics

IS - 25

ER -

Organometallic macrocycle chemistry. 5.¹ σ-vinyl and σ-aryl complexes of ruthenium(II) ligated by 1,4,7-trithiacyclononane: X-ray crystal structure of [Ru(CH=CH₂)(CO)(PPh₃)([9]aneS ₃)]PF6·2CH₂Cl₂

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