Organometallics roundtable 2011

John A. Gladysz; Zachary T. Ball; Guy Bertrand; Suzanne A. Blum; Vy M. Dong; Reto Dorta; F. Ekkehardt Hahn; Mark G. Humphrey; William D. Jones; Jerzy Klosin; Ian Manners; Tobin J. Marks; James M. Mayer; Bernhard Rieger; Joachim C. Ritter; Alfred P. Sattelberger; Jennifer M. Schomaker; Vivian Wing Wah Yam

doi:10.1021/om201234x

Organometallics roundtable 2011

John A. Gladysz^*, Zachary T. Ball, Guy Bertrand, Suzanne A. Blum, Vy M. Dong, Reto Dorta, F. Ekkehardt Hahn, Mark G. Humphrey, William D. Jones, Jerzy Klosin, Ian Manners, Tobin J. Marks, James M. Mayer, Bernhard Rieger, Joachim C. Ritter, Alfred P. Sattelberger, Jennifer M. Schomaker, Vivian Wing Wah Yam

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

33 Citations (Scopus)

Abstract

An edited transcript of the discussions at the Organometallics Roundtable 2011 held on August 29, 2011 is presented. Jennifer Schomaker says that she would like to have a broader range of high-valent metal oxo complexes that contain easily tunable non-porphyrin ligands. Jim Mayer was thinking more about pure and simple chemical stability. People are doing reactions at higher temperatures and under more forcing conditions, with more stable ligands, such as the pincer ligands having been developed by Alan Goldman, Jensen and Kaska, and Brookhart. Vy Dong says that his students had a debate regarding this very question last year, and they chose the Mo-catalyzed Z-selective olefin metathesis reaction developed by Amir Hoveyda and Richard Schrock as the top achievement in organometallic chemistry last year. There are many exciting aspects of that work. For one, the complex itself has a unique structure, bearing a pyrrolide, a tunable imido, and an axially chiral binol-derived ligand.

Original language	English
Pages (from-to)	1-18
Number of pages	18
Journal	Organometallics
Volume	31
Issue number	1
DOIs	https://doi.org/10.1021/om201234x
Publication status	Published - 9 Jan 2012

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title = "Organometallics roundtable 2011",

abstract = "An edited transcript of the discussions at the Organometallics Roundtable 2011 held on August 29, 2011 is presented. Jennifer Schomaker says that she would like to have a broader range of high-valent metal oxo complexes that contain easily tunable non-porphyrin ligands. Jim Mayer was thinking more about pure and simple chemical stability. People are doing reactions at higher temperatures and under more forcing conditions, with more stable ligands, such as the pincer ligands having been developed by Alan Goldman, Jensen and Kaska, and Brookhart. Vy Dong says that his students had a debate regarding this very question last year, and they chose the Mo-catalyzed Z-selective olefin metathesis reaction developed by Amir Hoveyda and Richard Schrock as the top achievement in organometallic chemistry last year. There are many exciting aspects of that work. For one, the complex itself has a unique structure, bearing a pyrrolide, a tunable imido, and an axially chiral binol-derived ligand.",

author = "Gladysz, \{John A.\} and Ball, \{Zachary T.\} and Guy Bertrand and Blum, \{Suzanne A.\} and Dong, \{Vy M.\} and Reto Dorta and Hahn, \{F. Ekkehardt\} and Humphrey, \{Mark G.\} and Jones, \{William D.\} and Jerzy Klosin and Ian Manners and Marks, \{Tobin J.\} and Mayer, \{James M.\} and Bernhard Rieger and Ritter, \{Joachim C.\} and Sattelberger, \{Alfred P.\} and Schomaker, \{Jennifer M.\} and Yam, \{Vivian Wing Wah\}",

year = "2012",

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doi = "10.1021/om201234x",

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AU - Gladysz, John A.

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AU - Bertrand, Guy

AU - Blum, Suzanne A.

AU - Dong, Vy M.

AU - Dorta, Reto

AU - Hahn, F. Ekkehardt

AU - Humphrey, Mark G.

AU - Jones, William D.

AU - Klosin, Jerzy

AU - Manners, Ian

AU - Marks, Tobin J.

AU - Mayer, James M.

AU - Rieger, Bernhard

AU - Ritter, Joachim C.

AU - Sattelberger, Alfred P.

AU - Schomaker, Jennifer M.

AU - Yam, Vivian Wing Wah

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N2 - An edited transcript of the discussions at the Organometallics Roundtable 2011 held on August 29, 2011 is presented. Jennifer Schomaker says that she would like to have a broader range of high-valent metal oxo complexes that contain easily tunable non-porphyrin ligands. Jim Mayer was thinking more about pure and simple chemical stability. People are doing reactions at higher temperatures and under more forcing conditions, with more stable ligands, such as the pincer ligands having been developed by Alan Goldman, Jensen and Kaska, and Brookhart. Vy Dong says that his students had a debate regarding this very question last year, and they chose the Mo-catalyzed Z-selective olefin metathesis reaction developed by Amir Hoveyda and Richard Schrock as the top achievement in organometallic chemistry last year. There are many exciting aspects of that work. For one, the complex itself has a unique structure, bearing a pyrrolide, a tunable imido, and an axially chiral binol-derived ligand.

AB - An edited transcript of the discussions at the Organometallics Roundtable 2011 held on August 29, 2011 is presented. Jennifer Schomaker says that she would like to have a broader range of high-valent metal oxo complexes that contain easily tunable non-porphyrin ligands. Jim Mayer was thinking more about pure and simple chemical stability. People are doing reactions at higher temperatures and under more forcing conditions, with more stable ligands, such as the pincer ligands having been developed by Alan Goldman, Jensen and Kaska, and Brookhart. Vy Dong says that his students had a debate regarding this very question last year, and they chose the Mo-catalyzed Z-selective olefin metathesis reaction developed by Amir Hoveyda and Richard Schrock as the top achievement in organometallic chemistry last year. There are many exciting aspects of that work. For one, the complex itself has a unique structure, bearing a pyrrolide, a tunable imido, and an axially chiral binol-derived ligand.

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Organometallics roundtable 2011

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