Orientation of doubly excited states in N 2

John E. Furst*, T. J. Gay, Joshua MacHacek, David Kilkoyne, Kenneth W. McLaughlin

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

We have measured the total fluorescent intensity and circular polarization of light emitted in 3p4Po→3s4P transitions of excited neutral nitrogen atoms created by the photofragmentation of the N 2 molecule with circularly polarized light having energies between 21 and 26 eV. The intensity measurements show the effect of predissociation of the N 2 Rydberg series R(C) 1Σu+ states by non-Rydberg doubly excited resonances (NRDERs), while nonzero values of circular polarization allow us to unambiguously identify the presence of a directly excited NRDER with 1Π u symmetry in this energy range.

Original languageEnglish
Article number041401
JournalPhysical Review A - Atomic, Molecular, and Optical Physics
Volume86
Issue number4
DOIs
Publication statusPublished - 2 Oct 2012
Externally publishedYes

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