Osmium-catalyzed vicinal oxyamination of alkenes by N-(4- toluenesulfonyloxy)carbamates

Masruri, Anthony C. Willis, Malcolm D. McLeod*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    32 Citations (Scopus)

    Abstract

    N-(4-Toluenesulfonyloxy)carbamates based on a range of common amine protecting groups serve as preformed nitrogen sources in the intermolecular osmium-catalyzed oxyamination reaction of a variety of mono-, di-, and trisubstituted alkenes. The reactions occur with low catalyst loadings and good yields and afford high regioselectivity for unsymmetrically substituted alkenes.

    Original languageEnglish
    Pages (from-to)8480-8491
    Number of pages12
    JournalJournal of Organic Chemistry
    Volume77
    Issue number19
    DOIs
    Publication statusPublished - 5 Oct 2012

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