Abstract
N-(4-Toluenesulfonyloxy)carbamates based on a range of common amine protecting groups serve as preformed nitrogen sources in the intermolecular osmium-catalyzed oxyamination reaction of a variety of mono-, di-, and trisubstituted alkenes. The reactions occur with low catalyst loadings and good yields and afford high regioselectivity for unsymmetrically substituted alkenes.
Original language | English |
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Pages (from-to) | 8480-8491 |
Number of pages | 12 |
Journal | Journal of Organic Chemistry |
Volume | 77 |
Issue number | 19 |
DOIs | |
Publication status | Published - 5 Oct 2012 |