Partial etherification reactions of cavitand phenol bowls

Elizabeth S. Barrett; Jacob L. Irwin; Kelvin Picker; Michael S. Sherburn

doi:10.1071/CH02031

Partial etherification reactions of cavitand phenol bowls

Elizabeth S. Barrett
, Jacob L. Irwin
, Kelvin Picker
, Michael S. Sherburn^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Reactions between the C_4v-symmetrical cavitand tetraphenol (2), various bases, and less than 4 molar equivalents of alkyl halides result in the generation of statistical mixtures of the five possible ether products along with unreacted starting material. Useful quantities of monoalkoxytriphenol (8), A,B-dialkoxydiphenol (9) and trialkoxymonophenol (11) are obtained by controlling the reaction stoichiometry and the desired products can, in general, be isolated by straightforward chromatographic means.

Original language	English
Pages (from-to)	319-325
Number of pages	7
Journal	Australian Journal of Chemistry
Volume	55
Issue number	5
DOIs	https://doi.org/10.1071/CH02031
Publication status	Published - 2002
Externally published	Yes

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10.1071/CH02031

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title = "Partial etherification reactions of cavitand phenol bowls",

abstract = "Reactions between the C4v-symmetrical cavitand tetraphenol (2), various bases, and less than 4 molar equivalents of alkyl halides result in the generation of statistical mixtures of the five possible ether products along with unreacted starting material. Useful quantities of monoalkoxytriphenol (8), A,B-dialkoxydiphenol (9) and trialkoxymonophenol (11) are obtained by controlling the reaction stoichiometry and the desired products can, in general, be isolated by straightforward chromatographic means.",

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journal = "Australian Journal of Chemistry",

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T1 - Partial etherification reactions of cavitand phenol bowls

AU - Barrett, Elizabeth S.

AU - Irwin, Jacob L.

AU - Picker, Kelvin

AU - Sherburn, Michael S.

PY - 2002

Y1 - 2002

N2 - Reactions between the C4v-symmetrical cavitand tetraphenol (2), various bases, and less than 4 molar equivalents of alkyl halides result in the generation of statistical mixtures of the five possible ether products along with unreacted starting material. Useful quantities of monoalkoxytriphenol (8), A,B-dialkoxydiphenol (9) and trialkoxymonophenol (11) are obtained by controlling the reaction stoichiometry and the desired products can, in general, be isolated by straightforward chromatographic means.

AB - Reactions between the C4v-symmetrical cavitand tetraphenol (2), various bases, and less than 4 molar equivalents of alkyl halides result in the generation of statistical mixtures of the five possible ether products along with unreacted starting material. Useful quantities of monoalkoxytriphenol (8), A,B-dialkoxydiphenol (9) and trialkoxymonophenol (11) are obtained by controlling the reaction stoichiometry and the desired products can, in general, be isolated by straightforward chromatographic means.

UR - https://www.scopus.com/pages/publications/0036037120

U2 - 10.1071/CH02031

DO - 10.1071/CH02031

M3 - Article

SN - 0004-9425

VL - 55

SP - 319

EP - 325

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 5

ER -

Partial etherification reactions of cavitand phenol bowls

Abstract

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