Patterned photochemical deposition on domain engineered ferroelectric single crystals

Kenny Lau; Yun Liu; Qian Li; Ray L. Withers; Zhenrong Li; Zhuo Xu

doi:10.1109/ISAF.2014.6922992

Patterned photochemical deposition on domain engineered ferroelectric single crystals

Kenny Lau^*, Yun Liu, Qian Li, Ray L. Withers, Zhenrong Li, Zhuo Xu

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

The photochemical deposition of silver on (001)-oriented 0.25Pb(In_1/2Nb_1/2)O₃-0.44Pb(Mg_1/3Nb_2/3)O₃-0.31PbTiO₃ (PIN-PMN-PT) ferroelectric single crystals is investigated via piezoresponse force microscopy (PFM) and Kelvin probe force microscopy (KPFM). Selective photochemical deposition within c⁺ domains is attained by manipulating the photoreaction time. Enhanced photochemical reduction at c^-/c⁺ domain boundaries is achieved by controlling the domain poling voltage and the scanning direction of the tip during domain switching. These phenomena are explained by polarisation band bending at domain boundaries and tip induced charge injection during domain switching. This work provides insight into obtaining an arbitrary spatial distribution of photodeposited metal on ferroelectric materials.

Original language	English
Title of host publication	2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014
Publisher	Institute of Electrical and Electronics Engineers Inc.
ISBN (Electronic)	9781479938605
DOIs	https://doi.org/10.1109/ISAF.2014.6922992
Publication status	Published - 13 Oct 2014
Event	2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014 - State College, United States Duration: 12 May 2014 → 16 May 2014

Publication series

Name	2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014

Conference

Conference	2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014
Country/Territory	United States
City	State College
Period	12/05/14 → 16/05/14

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10.1109/ISAF.2014.6922992

Cite this

Lau, K., Liu, Y., Li, Q., Withers, R. L., Li, Z., & Xu, Z. (2014). Patterned photochemical deposition on domain engineered ferroelectric single crystals. In 2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014 Article 6922992 (2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/ISAF.2014.6922992

Lau, Kenny ; Liu, Yun ; Li, Qian et al. / Patterned photochemical deposition on domain engineered ferroelectric single crystals. 2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014. Institute of Electrical and Electronics Engineers Inc., 2014. (2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014).

@inproceedings{215c7ed9b66e4e3097d421bb91cc5b70,

title = "Patterned photochemical deposition on domain engineered ferroelectric single crystals",

abstract = "The photochemical deposition of silver on (001)-oriented 0.25Pb(In1/2Nb1/2)O3-0.44Pb(Mg1/3Nb2/3)O3-0.31PbTiO3 (PIN-PMN-PT) ferroelectric single crystals is investigated via piezoresponse force microscopy (PFM) and Kelvin probe force microscopy (KPFM). Selective photochemical deposition within c+ domains is attained by manipulating the photoreaction time. Enhanced photochemical reduction at c-/c+ domain boundaries is achieved by controlling the domain poling voltage and the scanning direction of the tip during domain switching. These phenomena are explained by polarisation band bending at domain boundaries and tip induced charge injection during domain switching. This work provides insight into obtaining an arbitrary spatial distribution of photodeposited metal on ferroelectric materials.",

keywords = "domain switching, ferroelectrics, photochemical deposition, photoreduction, surface potential",

author = "Kenny Lau and Yun Liu and Qian Li and Withers, {Ray L.} and Zhenrong Li and Zhuo Xu",

note = "Publisher Copyright: {\textcopyright} 2014 IEEE.; 2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014 ; Conference date: 12-05-2014 Through 16-05-2014",

year = "2014",

month = oct,

day = "13",

doi = "10.1109/ISAF.2014.6922992",

language = "English",

series = "2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014",

publisher = "Institute of Electrical and Electronics Engineers Inc.",

booktitle = "2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014",

address = "United States",

}

Lau, K, Liu, Y, Li, Q, Withers, RL, Li, Z & Xu, Z 2014, Patterned photochemical deposition on domain engineered ferroelectric single crystals. in 2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014., 6922992, 2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014, Institute of Electrical and Electronics Engineers Inc., 2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014, State College, United States, 12/05/14. https://doi.org/10.1109/ISAF.2014.6922992

Patterned photochemical deposition on domain engineered ferroelectric single crystals. / Lau, Kenny; Liu, Yun; Li, Qian et al.
2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014. Institute of Electrical and Electronics Engineers Inc., 2014. 6922992 (2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Patterned photochemical deposition on domain engineered ferroelectric single crystals

AU - Lau, Kenny

AU - Liu, Yun

AU - Li, Qian

AU - Withers, Ray L.

AU - Li, Zhenrong

AU - Xu, Zhuo

PY - 2014/10/13

Y1 - 2014/10/13

N2 - The photochemical deposition of silver on (001)-oriented 0.25Pb(In1/2Nb1/2)O3-0.44Pb(Mg1/3Nb2/3)O3-0.31PbTiO3 (PIN-PMN-PT) ferroelectric single crystals is investigated via piezoresponse force microscopy (PFM) and Kelvin probe force microscopy (KPFM). Selective photochemical deposition within c+ domains is attained by manipulating the photoreaction time. Enhanced photochemical reduction at c-/c+ domain boundaries is achieved by controlling the domain poling voltage and the scanning direction of the tip during domain switching. These phenomena are explained by polarisation band bending at domain boundaries and tip induced charge injection during domain switching. This work provides insight into obtaining an arbitrary spatial distribution of photodeposited metal on ferroelectric materials.

AB - The photochemical deposition of silver on (001)-oriented 0.25Pb(In1/2Nb1/2)O3-0.44Pb(Mg1/3Nb2/3)O3-0.31PbTiO3 (PIN-PMN-PT) ferroelectric single crystals is investigated via piezoresponse force microscopy (PFM) and Kelvin probe force microscopy (KPFM). Selective photochemical deposition within c+ domains is attained by manipulating the photoreaction time. Enhanced photochemical reduction at c-/c+ domain boundaries is achieved by controlling the domain poling voltage and the scanning direction of the tip during domain switching. These phenomena are explained by polarisation band bending at domain boundaries and tip induced charge injection during domain switching. This work provides insight into obtaining an arbitrary spatial distribution of photodeposited metal on ferroelectric materials.

KW - domain switching

KW - ferroelectrics

KW - photochemical deposition

KW - photoreduction

KW - surface potential

UR - http://www.scopus.com/inward/record.url?scp=84909992942&partnerID=8YFLogxK

U2 - 10.1109/ISAF.2014.6922992

DO - 10.1109/ISAF.2014.6922992

M3 - Conference contribution

T3 - 2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014

BT - 2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014

PB - Institute of Electrical and Electronics Engineers Inc.

T2 - 2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014

Y2 - 12 May 2014 through 16 May 2014

ER -

Lau K, Liu Y, Li Q, Withers RL, Li Z, Xu Z. Patterned photochemical deposition on domain engineered ferroelectric single crystals. In 2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014. Institute of Electrical and Electronics Engineers Inc. 2014. 6922992. (2014 Joint IEEE International Symposium on the Applications of Ferroelectric, International Workshop on Acoustic Transduction Materials and Devices and Workshop on Piezoresponse Force Microscopy, ISAF/IWATMD/PFM 2014). doi: 10.1109/ISAF.2014.6922992

Patterned photochemical deposition on domain engineered ferroelectric single crystals

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