Petrology, Age, and Rift Origin of Ultramafic Lamprophyres (Aillikites) at Mount Webb, a New Alkaline Province in Central Australia

Diamond exploration over the past decade has led to the discovery of a new province of kimberlitic pipes (the Webb Province) in the Gibson Desert of central Australia. The Webb pipes comprise sparse macrocrystic olivine set in a groundmass of olivine, phlogopite, perovskite, spinel, clinopyroxene, titanian-andradite and carbonate. The pipes resemble ultramafic lamprophyres (notably aillikites) in their mineralogy, major and minor oxide chemistry, and initial ⁸⁷Sr/⁸⁶Sr and εNd-εHf isotopic compositions. Ion probe U-Pb geochronology on perovskite (806 ± 22 Ma) indicates the eruption of the pipes was co-eval with plume-related magmatism within central Australia (Willouran-Gairdner Volcanic Event) associated with the opening of the Centralian Superbasin and Rodinia supercontinent break-up. The equilibration pressure and temperature of mantle-derived garnet and chromian (Cr) diopside xenocrysts range between 17 and 40 kbar and 750–1320°C and define a paleo-lithospheric thickness of 140 ± 10 km. Chemical variations of xenocrysts define litho-chemical horizons within the shallow, middle, and deep sub-continental lithospheric mantle (SCLM). The shallow SCLM (50–70 km), which includes garnet-spinel and spinel lherzolite, contains Cr diopside with weakly refertilized rare earth element compositions and unenriched compositions. The mid-lithosphere (70–85 km) has lower modal abundances of Cr diopside. This layer corresponds to a seismic mid-lithosphere discontinuity interpreted as pargasite-bearing lherzolite. The deep SCLM (>90 km) comprises refertilized garnet lherzolite that was metasomatized by a silicate-carbonatite melt.