Plastic deformation and corrosion in austenitic stainless steel: A novel approach through microtexture and infrared spectroscopy

N. Srinivasan; V. Kain; N. Birbilis; B. Sunil Kumar; M. N. Gandhi; P. V. Sivaprasad; G. Chai; A. Lodh; P. M. Ahmedabadi; I. Samajdar

doi:10.1016/j.corsci.2016.05.027

Plastic deformation and corrosion in austenitic stainless steel: A novel approach through microtexture and infrared spectroscopy

N. Srinivasan, V. Kain, N. Birbilis, B. Sunil Kumar, M. N. Gandhi, P. V. Sivaprasad, G. Chai, A. Lodh, P. M. Ahmedabadi, I. Samajdar^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The anodic potentiodynamic polarization behaviors of austenitic stainless steels, with varying Cu (copper) and/or Mo (molybdenum) additions, were explored after plane strain compression. Though all the alloys showed developments in deformed microstructures, the presence of Cu + Mo did not result in strain induced martensite formation (SIMF). However, the presence of Cu + Mo revealed the highest degradation in corrosion performance. A combination of microtexture measurements and fourier transform infrared spectroscopy (FTIR)-imaging revealed that the presence of SIMF promoted post-passivation stability or retention of a protective Cr₂O₃ film.

Original language	English
Pages (from-to)	404-413
Number of pages	10
Journal	Corrosion Science
Volume	111
DOIs	https://doi.org/10.1016/j.corsci.2016.05.027
Publication status	Published - 1 Oct 2016
Externally published	Yes

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10.1016/j.corsci.2016.05.027

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title = "Plastic deformation and corrosion in austenitic stainless steel: A novel approach through microtexture and infrared spectroscopy",

abstract = "The anodic potentiodynamic polarization behaviors of austenitic stainless steels, with varying Cu (copper) and/or Mo (molybdenum) additions, were explored after plane strain compression. Though all the alloys showed developments in deformed microstructures, the presence of Cu + Mo did not result in strain induced martensite formation (SIMF). However, the presence of Cu + Mo revealed the highest degradation in corrosion performance. A combination of microtexture measurements and fourier transform infrared spectroscopy (FTIR)-imaging revealed that the presence of SIMF promoted post-passivation stability or retention of a protective Cr2O3 film.",

keywords = "A. Stainless steels, B. Electron backscattered diffraction, B. IR spectroscopy, B. Polarization, C. Passive film, C. effects of strain, SIMS",

author = "N. Srinivasan and V. Kain and N. Birbilis and Kumar, {B. Sunil} and Gandhi, {M. N.} and Sivaprasad, {P. V.} and G. Chai and A. Lodh and Ahmedabadi, {P. M.} and I. Samajdar",

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year = "2016",

month = oct,

day = "1",

doi = "10.1016/j.corsci.2016.05.027",

language = "English",

volume = "111",

pages = "404--413",

journal = "Corrosion Science",

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TY - JOUR

T1 - Plastic deformation and corrosion in austenitic stainless steel

T2 - A novel approach through microtexture and infrared spectroscopy

AU - Srinivasan, N.

AU - Kain, V.

AU - Birbilis, N.

AU - Kumar, B. Sunil

AU - Gandhi, M. N.

AU - Sivaprasad, P. V.

AU - Chai, G.

AU - Lodh, A.

AU - Ahmedabadi, P. M.

AU - Samajdar, I.

PY - 2016/10/1

Y1 - 2016/10/1

N2 - The anodic potentiodynamic polarization behaviors of austenitic stainless steels, with varying Cu (copper) and/or Mo (molybdenum) additions, were explored after plane strain compression. Though all the alloys showed developments in deformed microstructures, the presence of Cu + Mo did not result in strain induced martensite formation (SIMF). However, the presence of Cu + Mo revealed the highest degradation in corrosion performance. A combination of microtexture measurements and fourier transform infrared spectroscopy (FTIR)-imaging revealed that the presence of SIMF promoted post-passivation stability or retention of a protective Cr2O3 film.

AB - The anodic potentiodynamic polarization behaviors of austenitic stainless steels, with varying Cu (copper) and/or Mo (molybdenum) additions, were explored after plane strain compression. Though all the alloys showed developments in deformed microstructures, the presence of Cu + Mo did not result in strain induced martensite formation (SIMF). However, the presence of Cu + Mo revealed the highest degradation in corrosion performance. A combination of microtexture measurements and fourier transform infrared spectroscopy (FTIR)-imaging revealed that the presence of SIMF promoted post-passivation stability or retention of a protective Cr2O3 film.

KW - A. Stainless steels

KW - B. Electron backscattered diffraction

KW - B. IR spectroscopy

KW - B. Polarization

KW - C. Passive film

KW - C. effects of strain

KW - SIMS

UR - http://www.scopus.com/inward/record.url?scp=84976503452&partnerID=8YFLogxK

U2 - 10.1016/j.corsci.2016.05.027

DO - 10.1016/j.corsci.2016.05.027

M3 - Article

SN - 0010-938X

VL - 111

SP - 404

EP - 413

JO - Corrosion Science

JF - Corrosion Science

ER -

Plastic deformation and corrosion in austenitic stainless steel: A novel approach through microtexture and infrared spectroscopy

Abstract

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