Abstract
The reactions of a range of cyanometallate salts with ClAtBu2 (A = P, As, Sb, A not equal Bi) afford the new phosphino, arsino and stibino-isonitrile complexes [M(CNAtBu2)(CO)5] (M = W, A = P, As, Sb) and [MLn(CNPtBu2)] [MLn = Cr(CO)5, Mo(CO)5, Mn(CO)2(eta 5-C5H5), Re(CO)2(eta 5-C5H5), Fe(CO)4, Fe(CO)3(PPh3)] allowing crystallographic spectroscopic and computational interrogation of isonitrile compexes functionalised by the heavier pnictogens.
Original language | English |
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Pages (from-to) | 8881-8887 |
Number of pages | 7 |
Journal | Dalton Transactions |
Volume | 54 |
Issue number | 22 |
DOIs | |
Publication status | Published - 3 Jun 2025 |