Polyazolyl chelate chemistry. 13. An osmaboratrane

Mark R.St J. Foreman; Anthony F. Hill; Andrew J.P. White; David J. Williams

doi:10.1021/om0306123

Polyazolyl chelate chemistry. 13. An osmaboratrane

Mark R.St J. Foreman, Anthony F. Hill^*, Andrew J.P. White, David J. Williams

^*Corresponding author for this work

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107 Citations (Scopus)

Abstract

The reaction of [Os(C₆H₅)Cl(CO)(PPh₃)₂] with Na[HB(mt)₃] (mt = methimazolyl) results in benzene elimination and the formation of the first osmaboratrane [B(mt)₃Os(CO)(PPh₃)](Os→B), the crystal structure of which reveals a somewhat long transannular dative bond between osmium(0) and boron(III).

Original language	English
Pages (from-to)	913-916
Number of pages	4
Journal	Organometallics
Volume	23
Issue number	4
DOIs	https://doi.org/10.1021/om0306123
Publication status	Published - 16 Feb 2004

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abstract = "The reaction of [Os(C6H5)Cl(CO)(PPh3)2] with Na[HB(mt)3] (mt = methimazolyl) results in benzene elimination and the formation of the first osmaboratrane [B(mt)3Os(CO)(PPh3)](Os→B), the crystal structure of which reveals a somewhat long transannular dative bond between osmium(0) and boron(III).",

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AU - Hill, Anthony F.

AU - White, Andrew J.P.

AU - Williams, David J.

PY - 2004/2/16

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N2 - The reaction of [Os(C6H5)Cl(CO)(PPh3)2] with Na[HB(mt)3] (mt = methimazolyl) results in benzene elimination and the formation of the first osmaboratrane [B(mt)3Os(CO)(PPh3)](Os→B), the crystal structure of which reveals a somewhat long transannular dative bond between osmium(0) and boron(III).

AB - The reaction of [Os(C6H5)Cl(CO)(PPh3)2] with Na[HB(mt)3] (mt = methimazolyl) results in benzene elimination and the formation of the first osmaboratrane [B(mt)3Os(CO)(PPh3)](Os→B), the crystal structure of which reveals a somewhat long transannular dative bond between osmium(0) and boron(III).

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DO - 10.1021/om0306123

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JO - Organometallics

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ER -

Polyazolyl chelate chemistry. 13. An osmaboratrane

Abstract

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