Polyhedral oligomeric silsesquioxane-bound iminofullerene

David J. Clarke; Janis G. Matisons; George P. Simon; Marek Samoc; Anna Samoc

doi:10.1002/aoc.1568

Polyhedral oligomeric silsesquioxane-bound iminofullerene

David J. Clarke, Janis G. Matisons, George P. Simon, Marek Samoc, Anna Samoc

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Polyhedral oligomeric silsesquioxane (POSS) cages containing an iminofullerene species are reported herein.Monosubstituted benzyl chloride POSS was synthesized, and subsequently reactedwith sodium azide to form mono benzyl azide POSS. The azide was subsequently reacted with C₆₀ in anhydrous, degassed toluene to yield the desired POSS iminofullerene compound. The prepared compounds were characterized by multinuclear NMR, electrospray mass spectrometry, elemental analysis, UV-vis, fluorescence and optical power limitingmeasurements.

Original language	English
Pages (from-to)	184-188
Number of pages	5
Journal	Applied Organometallic Chemistry
Volume	24
Issue number	3
DOIs	https://doi.org/10.1002/aoc.1568
Publication status	Published - Mar 2010

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title = "Polyhedral oligomeric silsesquioxane-bound iminofullerene",

abstract = "Polyhedral oligomeric silsesquioxane (POSS) cages containing an iminofullerene species are reported herein.Monosubstituted benzyl chloride POSS was synthesized, and subsequently reactedwith sodium azide to form mono benzyl azide POSS. The azide was subsequently reacted with C60 in anhydrous, degassed toluene to yield the desired POSS iminofullerene compound. The prepared compounds were characterized by multinuclear NMR, electrospray mass spectrometry, elemental analysis, UV-vis, fluorescence and optical power limitingmeasurements.",

keywords = "Fullerene, Power limiting, Silsesquioxane",

author = "Clarke, {David J.} and Matisons, {Janis G.} and Simon, {George P.} and Marek Samoc and Anna Samoc",

year = "2010",

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language = "English",

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T1 - Polyhedral oligomeric silsesquioxane-bound iminofullerene

AU - Clarke, David J.

AU - Matisons, Janis G.

AU - Simon, George P.

AU - Samoc, Marek

AU - Samoc, Anna

PY - 2010/3

Y1 - 2010/3

N2 - Polyhedral oligomeric silsesquioxane (POSS) cages containing an iminofullerene species are reported herein.Monosubstituted benzyl chloride POSS was synthesized, and subsequently reactedwith sodium azide to form mono benzyl azide POSS. The azide was subsequently reacted with C60 in anhydrous, degassed toluene to yield the desired POSS iminofullerene compound. The prepared compounds were characterized by multinuclear NMR, electrospray mass spectrometry, elemental analysis, UV-vis, fluorescence and optical power limitingmeasurements.

AB - Polyhedral oligomeric silsesquioxane (POSS) cages containing an iminofullerene species are reported herein.Monosubstituted benzyl chloride POSS was synthesized, and subsequently reactedwith sodium azide to form mono benzyl azide POSS. The azide was subsequently reacted with C60 in anhydrous, degassed toluene to yield the desired POSS iminofullerene compound. The prepared compounds were characterized by multinuclear NMR, electrospray mass spectrometry, elemental analysis, UV-vis, fluorescence and optical power limitingmeasurements.

KW - Fullerene

KW - Power limiting

KW - Silsesquioxane

UR - http://www.scopus.com/inward/record.url?scp=77449150972&partnerID=8YFLogxK

U2 - 10.1002/aoc.1568

DO - 10.1002/aoc.1568

M3 - Article

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VL - 24

SP - 184

EP - 188

JO - Applied Organometallic Chemistry

JF - Applied Organometallic Chemistry

IS - 3

ER -

Polyhedral oligomeric silsesquioxane-bound iminofullerene

Abstract

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