Poly(methimazolyl)borate complexes of platinum

Ian R. Crossley; Anthony F. Hill; Anthony C. Willis

doi:10.1021/om050377j

Poly(methimazolyl)borate complexes of platinum

Ian R. Crossley, Anthony F. Hill^*, Anthony C. Willis

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

The reaction of iodotrimethylplatinum(IV) with 1 equiv of Na[HB(mt) ₃] or Na[H₂B(mt)₂] (mt = methimazolyl) affords respectively the octahedral organometallic complexes [PtMe₃{HB(mt) ₃}] and [PtMe₃-{H₂B(mt)₂}], the first isolated examples of poly(methimazolyl)borate complexes of platinum, which prove remarkably stable toward the reductive elimination of methane. The latter reacts further with [PtMe₃I]₄ to afford the novel, sulfur-bridged dinuclear complex [Me₃-Pt{μ-H₂B(mt) ₂}PtMe₃I].

Original language	English
Pages (from-to)	4889-4892
Number of pages	4
Journal	Organometallics
Volume	24
Issue number	21
DOIs	https://doi.org/10.1021/om050377j
Publication status	Published - 10 Oct 2005

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title = "Poly(methimazolyl)borate complexes of platinum",

abstract = "The reaction of iodotrimethylplatinum(IV) with 1 equiv of Na[HB(mt) 3] or Na[H2B(mt)2] (mt = methimazolyl) affords respectively the octahedral organometallic complexes [PtMe3{HB(mt) 3}] and [PtMe3-{H2B(mt)2}], the first isolated examples of poly(methimazolyl)borate complexes of platinum, which prove remarkably stable toward the reductive elimination of methane. The latter reacts further with [PtMe3I]4 to afford the novel, sulfur-bridged dinuclear complex [Me3-Pt{μ-H2B(mt) 2}PtMe3I].",

author = "Crossley, {Ian R.} and Hill, {Anthony F.} and Willis, {Anthony C.}",

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T1 - Poly(methimazolyl)borate complexes of platinum

AU - Crossley, Ian R.

AU - Hill, Anthony F.

AU - Willis, Anthony C.

PY - 2005/10/10

Y1 - 2005/10/10

N2 - The reaction of iodotrimethylplatinum(IV) with 1 equiv of Na[HB(mt) 3] or Na[H2B(mt)2] (mt = methimazolyl) affords respectively the octahedral organometallic complexes [PtMe3{HB(mt) 3}] and [PtMe3-{H2B(mt)2}], the first isolated examples of poly(methimazolyl)borate complexes of platinum, which prove remarkably stable toward the reductive elimination of methane. The latter reacts further with [PtMe3I]4 to afford the novel, sulfur-bridged dinuclear complex [Me3-Pt{μ-H2B(mt) 2}PtMe3I].

AB - The reaction of iodotrimethylplatinum(IV) with 1 equiv of Na[HB(mt) 3] or Na[H2B(mt)2] (mt = methimazolyl) affords respectively the octahedral organometallic complexes [PtMe3{HB(mt) 3}] and [PtMe3-{H2B(mt)2}], the first isolated examples of poly(methimazolyl)borate complexes of platinum, which prove remarkably stable toward the reductive elimination of methane. The latter reacts further with [PtMe3I]4 to afford the novel, sulfur-bridged dinuclear complex [Me3-Pt{μ-H2B(mt) 2}PtMe3I].

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DO - 10.1021/om050377j

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VL - 24

SP - 4889

EP - 4892

JO - Organometallics

JF - Organometallics

IS - 21

ER -

Poly(methimazolyl)borate complexes of platinum

Abstract

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