Poly(methimazolyl)silanes: Syntheses and molecular structures

Jörg Wagler; Thomas Heine; Anthony F. Hill

doi:10.1021/om1004989

Poly(methimazolyl)silanes: Syntheses and molecular structures

Jörg Wagler^*, Thomas Heine, Anthony F. Hill

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A new class of multidentate "scorpionate" ligands is readily obtained from the reactions of methimazole with a range of organochlorosilanes. A recurrent structural feature to emerge is the intramolecular S-capping of the tetrahedral inner Si coordination spheres, the nature of which is responsive to the substitution pattern at silicon.

Original language	English
Pages (from-to)	5607-5613
Number of pages	7
Journal	Organometallics
Volume	29
Issue number	21
DOIs	https://doi.org/10.1021/om1004989
Publication status	Published - 8 Nov 2010

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T2 - Syntheses and molecular structures

AU - Wagler, Jörg

AU - Heine, Thomas

AU - Hill, Anthony F.

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N2 - A new class of multidentate "scorpionate" ligands is readily obtained from the reactions of methimazole with a range of organochlorosilanes. A recurrent structural feature to emerge is the intramolecular S-capping of the tetrahedral inner Si coordination spheres, the nature of which is responsive to the substitution pattern at silicon.

AB - A new class of multidentate "scorpionate" ligands is readily obtained from the reactions of methimazole with a range of organochlorosilanes. A recurrent structural feature to emerge is the intramolecular S-capping of the tetrahedral inner Si coordination spheres, the nature of which is responsive to the substitution pattern at silicon.

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U2 - 10.1021/om1004989

DO - 10.1021/om1004989

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JO - Organometallics

JF - Organometallics

IS - 21

ER -

Poly(methimazolyl)silanes: Syntheses and molecular structures

Abstract

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