Poly(methimazolyl)silanes: Syntheses and molecular structures

Jörg Wagler; Thomas Heine; Anthony F. Hill

doi:10.1021/om1004989

Poly(methimazolyl)silanes: Syntheses and molecular structures

Jörg Wagler^*, Thomas Heine, Anthony F. Hill

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A new class of multidentate "scorpionate" ligands is readily obtained from the reactions of methimazole with a range of organochlorosilanes. A recurrent structural feature to emerge is the intramolecular S-capping of the tetrahedral inner Si coordination spheres, the nature of which is responsive to the substitution pattern at silicon.

Original language	English
Pages (from-to)	5607-5613
Number of pages	7
Journal	Organometallics
Volume	29
Issue number	21
DOIs	https://doi.org/10.1021/om1004989
Publication status	Published - 8 Nov 2010

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abstract = "A new class of multidentate {"}scorpionate{"} ligands is readily obtained from the reactions of methimazole with a range of organochlorosilanes. A recurrent structural feature to emerge is the intramolecular S-capping of the tetrahedral inner Si coordination spheres, the nature of which is responsive to the substitution pattern at silicon.",

author = "J{\"o}rg Wagler and Thomas Heine and Hill, \{Anthony F.\}",

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T1 - Poly(methimazolyl)silanes

T2 - Syntheses and molecular structures

AU - Wagler, Jörg

AU - Heine, Thomas

AU - Hill, Anthony F.

PY - 2010/11/8

Y1 - 2010/11/8

N2 - A new class of multidentate "scorpionate" ligands is readily obtained from the reactions of methimazole with a range of organochlorosilanes. A recurrent structural feature to emerge is the intramolecular S-capping of the tetrahedral inner Si coordination spheres, the nature of which is responsive to the substitution pattern at silicon.

AB - A new class of multidentate "scorpionate" ligands is readily obtained from the reactions of methimazole with a range of organochlorosilanes. A recurrent structural feature to emerge is the intramolecular S-capping of the tetrahedral inner Si coordination spheres, the nature of which is responsive to the substitution pattern at silicon.

UR - https://www.scopus.com/pages/publications/78149295997

U2 - 10.1021/om1004989

DO - 10.1021/om1004989

M3 - Article

SN - 0276-7333

VL - 29

SP - 5607

EP - 5613

JO - Organometallics

JF - Organometallics

IS - 21

ER -

Poly(methimazolyl)silanes: Syntheses and molecular structures

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