Practical synthesis of the dendralene family reveals alternation in behavior

Alan D. Payne; Gomotsang Bojase; Michael N. Paddon-Row; Michael S. Sherburn

doi:10.1002/anie.200901733

Practical synthesis of the dendralene family reveals alternation in behavior

Alan D. Payne, Gomotsang Bojase, Michael N. Paddon-Row, Michael S. Sherburn

Research output: Contribution to journal › Article › peer-review

76 Citations (Scopus)

Abstract

Back from obscurity: The practical synthesis of the first six members of the fundamental class of acyclic branched oligoalkenes has been achieved. The syntheses allow access to the target compounds on multigram scales in good yields. Members of the family with even numbers of double bonds are significantly more stable than those with odd numbers (see picture), and exhibit different chemical reactivities in Diels-Alder reactions.

Original language	English
Pages (from-to)	4836-4839
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	26
DOIs	https://doi.org/10.1002/anie.200901733
Publication status	Published - 15 Jun 2009

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Practical synthesis of the dendralene family reveals alternation in behavior

Abstract

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