Probing the transition state via photoelectron and photodetachment spectroscopy of H3O-

Dong H. Zhang; Minghui Yang; Michael A. Collins; Soo Y. Lee

doi:10.1073/pnas.182297599

Probing the transition state via photoelectron and photodetachment spectroscopy of H₃O^-

Dong H. Zhang^*, Minghui Yang, Michael A. Collins, Soo Y. Lee

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The H₃O^- anion has stable and metastable structures that resemble configurations in the vicinity of the transition state for the neutral reactions OH + H₂ ↔ H₂O + H. Photoelectron spectroscopy of this anion probes the neutral reaction dynamics in the critical transition-state region. Accurate quantum dynamics calculations of the photoelectron intensity and photodissociation product energies are shown to provide a quantitatively reliable means of interpreting such experimental observations and reveal a detailed picture of the reaction dynamics.

Original language	English
Pages (from-to)	11579-11582
Number of pages	4
Journal	Proceedings of the National Academy of Sciences of the United States of America
Volume	99
Issue number	18
DOIs	https://doi.org/10.1073/pnas.182297599
Publication status	Published - 3 Sept 2002

Access to Document

10.1073/pnas.182297599

Cite this

@article{969b912b44c740399413fe626d3aab05,

title = "Probing the transition state via photoelectron and photodetachment spectroscopy of H3O-",

abstract = "The H3O- anion has stable and metastable structures that resemble configurations in the vicinity of the transition state for the neutral reactions OH + H2 ↔ H2O + H. Photoelectron spectroscopy of this anion probes the neutral reaction dynamics in the critical transition-state region. Accurate quantum dynamics calculations of the photoelectron intensity and photodissociation product energies are shown to provide a quantitatively reliable means of interpreting such experimental observations and reveal a detailed picture of the reaction dynamics.",

author = "Zhang, \{Dong H.\} and Minghui Yang and Collins, \{Michael A.\} and Lee, \{Soo Y.\}",

year = "2002",

month = sep,

day = "3",

doi = "10.1073/pnas.182297599",

language = "English",

volume = "99",

pages = "11579--11582",

journal = "Proceedings of the National Academy of Sciences of the United States of America",

issn = "0027-8424",

publisher = "National Academy of Sciences",

number = "18",

}

TY - JOUR

T1 - Probing the transition state via photoelectron and photodetachment spectroscopy of H3O-

AU - Zhang, Dong H.

AU - Yang, Minghui

AU - Collins, Michael A.

AU - Lee, Soo Y.

PY - 2002/9/3

Y1 - 2002/9/3

N2 - The H3O- anion has stable and metastable structures that resemble configurations in the vicinity of the transition state for the neutral reactions OH + H2 ↔ H2O + H. Photoelectron spectroscopy of this anion probes the neutral reaction dynamics in the critical transition-state region. Accurate quantum dynamics calculations of the photoelectron intensity and photodissociation product energies are shown to provide a quantitatively reliable means of interpreting such experimental observations and reveal a detailed picture of the reaction dynamics.

AB - The H3O- anion has stable and metastable structures that resemble configurations in the vicinity of the transition state for the neutral reactions OH + H2 ↔ H2O + H. Photoelectron spectroscopy of this anion probes the neutral reaction dynamics in the critical transition-state region. Accurate quantum dynamics calculations of the photoelectron intensity and photodissociation product energies are shown to provide a quantitatively reliable means of interpreting such experimental observations and reveal a detailed picture of the reaction dynamics.

UR - https://www.scopus.com/pages/publications/0037015033

U2 - 10.1073/pnas.182297599

DO - 10.1073/pnas.182297599

M3 - Article

SN - 0027-8424

VL - 99

SP - 11579

EP - 11582

JO - Proceedings of the National Academy of Sciences of the United States of America

JF - Proceedings of the National Academy of Sciences of the United States of America

IS - 18

ER -

Probing the transition state via photoelectron and photodetachment spectroscopy of H₃O^-

Abstract

Access to Document

Other files and links

Fingerprint

Cite this