Propargylidyne and tricarbido complexes

Richard A. Manzano; Anthony F. Hill

doi:10.1016/bs.adomc.2019.05.001

Propargylidyne and tricarbido complexes

Richard A. Manzano, Anthony F. Hill^*

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

17 Citations (Scopus)

Abstract

Propargylidynes, L_nM ≡ C-C ≡ CR, represent a special sub-class of carbyne complexes in which metal-carbon and carbon-carbon triple bonds are conjugated. Tricarbido complexes may be considered as a sub-class of propargylidynes in which the substituent “R” is a second metal center. In this review we comprehensively survey the chemistry of propargylidyne and tricarbido complexes up to October 2018, including points where their respective chemistries converge.

Original language	English
Title of host publication	Advances in Organometallic Chemistry
Editors	Pedro J. Pérez
Publisher	Academic Press Inc.
Pages	103-171
Number of pages	69
ISBN (Print)	9780128171172
DOIs	https://doi.org/10.1016/bs.adomc.2019.05.001
Publication status	Published - 2019

Publication series

Name	Advances in Organometallic Chemistry
Volume	72
ISSN (Print)	0065-3055

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10.1016/bs.adomc.2019.05.001

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title = "Propargylidyne and tricarbido complexes",

abstract = "Propargylidynes, LnM ≡ C-C ≡ CR, represent a special sub-class of carbyne complexes in which metal-carbon and carbon-carbon triple bonds are conjugated. Tricarbido complexes may be considered as a sub-class of propargylidynes in which the substituent “R” is a second metal center. In this review we comprehensively survey the chemistry of propargylidyne and tricarbido complexes up to October 2018, including points where their respective chemistries converge.",

keywords = "Alkylidyne, Bimetallic, Carbon-wires, Carbyne, Clusters, Propargylidyne, Tricarbido",

author = "Manzano, {Richard A.} and Hill, {Anthony F.}",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Inc.",

year = "2019",

doi = "10.1016/bs.adomc.2019.05.001",

language = "English",

isbn = "9780128171172",

series = "Advances in Organometallic Chemistry",

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TY - CHAP

T1 - Propargylidyne and tricarbido complexes

AU - Manzano, Richard A.

AU - Hill, Anthony F.

PY - 2019

Y1 - 2019

N2 - Propargylidynes, LnM ≡ C-C ≡ CR, represent a special sub-class of carbyne complexes in which metal-carbon and carbon-carbon triple bonds are conjugated. Tricarbido complexes may be considered as a sub-class of propargylidynes in which the substituent “R” is a second metal center. In this review we comprehensively survey the chemistry of propargylidyne and tricarbido complexes up to October 2018, including points where their respective chemistries converge.

AB - Propargylidynes, LnM ≡ C-C ≡ CR, represent a special sub-class of carbyne complexes in which metal-carbon and carbon-carbon triple bonds are conjugated. Tricarbido complexes may be considered as a sub-class of propargylidynes in which the substituent “R” is a second metal center. In this review we comprehensively survey the chemistry of propargylidyne and tricarbido complexes up to October 2018, including points where their respective chemistries converge.

KW - Alkylidyne

KW - Bimetallic

KW - Carbon-wires

KW - Carbyne

KW - Clusters

KW - Propargylidyne

KW - Tricarbido

UR - http://www.scopus.com/inward/record.url?scp=85068444955&partnerID=8YFLogxK

U2 - 10.1016/bs.adomc.2019.05.001

DO - 10.1016/bs.adomc.2019.05.001

M3 - Chapter

AN - SCOPUS:85068444955

SN - 9780128171172

T3 - Advances in Organometallic Chemistry

SP - 103

EP - 171

BT - Advances in Organometallic Chemistry

A2 - Pérez, Pedro J.

PB - Academic Press Inc.

ER -

Propargylidyne and tricarbido complexes

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