Rate-dependent phase transformations in nanoindented germanium

There is considerable controversy over the deformation behavior of germanium (Ge) under nanoindentation using a sharp diamond tip, with a diverse range of observations that suggest competing mechanisms. Here we show the deformation mechanism of Ge can be controlled by the rate of applied load. Loading rate is varied over three orders of magnitude using depth-sensing nanoindentation. At slow loading rates, shear-induced plasticity is observed. At rapid loading rates (>100 mN s_-1), pressure-induced phase transformations are detected by ex situ micro-Raman spectroscopy and transmission electron microscopy. This switch in the deformation mechanism is due to the differing rate sensitivities of the respective deformation modes, shear-induced plasticity or pressure-induced phase transformation.