Reaction of [Fe{C(=O)N′Pr2}(CO)4]- with trifluoroacetic Anhydride: Molecular structure of [Fe(CF3){η2-C(=O)N′Pr2}(CO)2(PPh3)]

Stephen Anderson; Anthony F. Hill; George R. Clark

doi:10.1021/om00042a005

Reaction of [Fe{C(=O)N′Pr₂}(CO)₄]^- with trifluoroacetic Anhydride: Molecular structure of [Fe(CF₃){η²-C(=O)N^′Pr₂}(CO)₂(PPh₃)]

Stephen Anderson, Anthony F. Hill^*, George R. Clark

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The reactions of the (carbamoyl)tetracarbonylferrate [Fe{C(=O)N′Pr₂}(CO)₄]^- with (CF₃CO)₂O and PPh₃ provide the structurally characterized trlfluoromethyl-carbamoyl complex [Fe(CF₃){η²-C(=O)N′Pr₂}-(CO)₂(PPh₃)]. A similar reaction with Ph₃SnCl and PPh₃ provides the stannyl derivative [Fe(SnPh₃) {η²-C(=O)N′Pr₂}(CO)₂(PPh₃)].

Original language	English
Pages (from-to)	1988-1990
Number of pages	3
Journal	Organometallics
Volume	11
Issue number	6
DOIs	https://doi.org/10.1021/om00042a005
Publication status	Published - 1 Jun 1992
Externally published	Yes

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title = "Reaction of [Fe{C(=O)N′Pr2}(CO)4]- with trifluoroacetic Anhydride: Molecular structure of [Fe(CF3){η2-C(=O)N′Pr2}(CO)2(PPh3)]",

abstract = "The reactions of the (carbamoyl)tetracarbonylferrate [Fe{C(=O)N′Pr2}(CO)4]- with (CF3CO)2O and PPh3 provide the structurally characterized trlfluoromethyl-carbamoyl complex [Fe(CF3){η2-C(=O)N′Pr2}-(CO)2(PPh3)]. A similar reaction with Ph3SnCl and PPh3 provides the stannyl derivative [Fe(SnPh3) {η2-C(=O)N′Pr2}(CO)2(PPh3)].",

author = "Stephen Anderson and Hill, {Anthony F.} and Clark, {George R.}",

year = "1992",

month = jun,

day = "1",

doi = "10.1021/om00042a005",

language = "English",

volume = "11",

pages = "1988--1990",

journal = "Organometallics",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - Reaction of [Fe{C(=O)N′Pr2}(CO)4]- with trifluoroacetic Anhydride

T2 - Molecular structure of [Fe(CF3){η2-C(=O)N′Pr2}(CO)2(PPh3)]

AU - Anderson, Stephen

AU - Hill, Anthony F.

AU - Clark, George R.

PY - 1992/6/1

Y1 - 1992/6/1

N2 - The reactions of the (carbamoyl)tetracarbonylferrate [Fe{C(=O)N′Pr2}(CO)4]- with (CF3CO)2O and PPh3 provide the structurally characterized trlfluoromethyl-carbamoyl complex [Fe(CF3){η2-C(=O)N′Pr2}-(CO)2(PPh3)]. A similar reaction with Ph3SnCl and PPh3 provides the stannyl derivative [Fe(SnPh3) {η2-C(=O)N′Pr2}(CO)2(PPh3)].

AB - The reactions of the (carbamoyl)tetracarbonylferrate [Fe{C(=O)N′Pr2}(CO)4]- with (CF3CO)2O and PPh3 provide the structurally characterized trlfluoromethyl-carbamoyl complex [Fe(CF3){η2-C(=O)N′Pr2}-(CO)2(PPh3)]. A similar reaction with Ph3SnCl and PPh3 provides the stannyl derivative [Fe(SnPh3) {η2-C(=O)N′Pr2}(CO)2(PPh3)].

UR - http://www.scopus.com/inward/record.url?scp=0010924603&partnerID=8YFLogxK

U2 - 10.1021/om00042a005

DO - 10.1021/om00042a005

M3 - Article

AN - SCOPUS:0010924603

SN - 0276-7333

VL - 11

SP - 1988

EP - 1990

JO - Organometallics

JF - Organometallics

IS - 6

ER -

Reaction of [Fe{C(=O)N′Pr₂}(CO)₄]^- with trifluoroacetic Anhydride: Molecular structure of [Fe(CF₃){η²-C(=O)N^′Pr₂}(CO)₂(PPh₃)]

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