TY - JOUR
T1 - Reactions of Mononuclear and Dinuclear Metal-Alkylidyne Complexes with Phosphaalkynes: C≡PP and C≡Mo Metathesis
AU - Hill, Anthony F.
AU - Howard, Judith A.K.
AU - Spaniol, Thomas P.
AU - Stone, F. Gordon A.
AU - Szameitat, Jürgen
PY - 1989/2
Y1 - 1989/2
N2 - The isolobal analogy between the fragments CR, P, and d5‐ML5 suggested the reaction of tBuC≡P with the Mo complex 1. Indeed, this reaction gave the metathesis product 2. The W complex 3 reacted with tBuC≡P to give an adduct 4, which can be regarded as an Fe(CO)3‐stabilized 1‐phospha‐3‐tungstacyclobutadiene.
AB - The isolobal analogy between the fragments CR, P, and d5‐ML5 suggested the reaction of tBuC≡P with the Mo complex 1. Indeed, this reaction gave the metathesis product 2. The W complex 3 reacted with tBuC≡P to give an adduct 4, which can be regarded as an Fe(CO)3‐stabilized 1‐phospha‐3‐tungstacyclobutadiene.
UR - https://www.scopus.com/pages/publications/84990111798
UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:A1989T733000023&DestLinkType=FullRecord&DestApp=WOS_CPL
U2 - 10.1002/anie.198902101
DO - 10.1002/anie.198902101
M3 - Comment/debate
AN - SCOPUS:84990111798
SN - 0570-0833
VL - 28
SP - 210
EP - 211
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 2
ER -