Reactions of [Ru(CO)2(PPh3)3] with alkynylphosphonium salts: A phosphinoallene complex

Wee Han Ang, Richard L. Cordiner, Anthony F. Hill, Tamara L. Perry, Jörg Wagler

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    14 Citations (Scopus)

    Abstract

    [Ru(CO)2(PPh3)3] reacts with either HC=CCH2Br or [HC=CCH2SMe2]Br to provide the σ-allenyl complex [Ru(CH=C=CH2)Br(CO)2(PPh 3)2]; however, with [HC=CCH2PPh3]Br, the salt [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]Br is obtained, which may be described as a complex of a phosphonioallene on the basis of crystallographic data for [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]2Br(PF6) and a comparison of spectroscopic data with those for the simple allene complex [Ru(γ2-H2C=C=CH2)(CO) 2(PPh3)2].

    Original languageEnglish
    Pages (from-to)5568-5574
    Number of pages7
    JournalOrganometallics
    Volume28
    Issue number18
    DOIs
    Publication statusPublished - 28 Sept 2009

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