Reactions of [Ru(CO)2(PPh3)3] with alkynylphosphonium salts: Phosphaallenylidene vs phosphonioacetylide coordination

Richard L. Cordiner; Anthony F. Hill; Jörg Wagler

doi:10.1021/om9003384

Reactions of [Ru(CO)₂(PPh₃)₃] with alkynylphosphonium salts: Phosphaallenylidene vs phosphonioacetylide coordination

Richard L. Cordiner, Anthony F. Hill, Jörg Wagler

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

[Ru(CO)₂(PPh₃)₃] reacts with [Me ₃SiC≡CPPh₃]-OTf in the presence of moist [ ⁿBu₄N]F to provide the C-H activation product [RuH(C≡CPPh₃)(CO)₂(PPh₃)₂]OTf spectroscopic and structural data for which are used to assess the previously proposed analogy between phosphonioacetylide and phosphaallenylidene (cf. isonitriles) bonding descriptions in an organometallic context.

Original language	English
Pages (from-to)	4880-4885
Number of pages	6
Journal	Organometallics
Volume	28
Issue number	16
DOIs	https://doi.org/10.1021/om9003384
Publication status	Published - 24 Aug 2009

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title = "Reactions of [Ru(CO)2(PPh3)3] with alkynylphosphonium salts: Phosphaallenylidene vs phosphonioacetylide coordination",

abstract = "[Ru(CO)2(PPh3)3] reacts with [Me 3SiC≡CPPh3]-OTf in the presence of moist [ nBu4N]F to provide the C-H activation product [RuH(C≡CPPh3)(CO)2(PPh3)2]OTf spectroscopic and structural data for which are used to assess the previously proposed analogy between phosphonioacetylide and phosphaallenylidene (cf. isonitriles) bonding descriptions in an organometallic context.",

author = "Cordiner, {Richard L.} and Hill, {Anthony F.} and J{\"o}rg Wagler",

year = "2009",

month = aug,

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doi = "10.1021/om9003384",

language = "English",

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journal = "Organometallics",

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T1 - Reactions of [Ru(CO)2(PPh3)3] with alkynylphosphonium salts

T2 - Phosphaallenylidene vs phosphonioacetylide coordination

AU - Cordiner, Richard L.

AU - Hill, Anthony F.

AU - Wagler, Jörg

PY - 2009/8/24

Y1 - 2009/8/24

N2 - [Ru(CO)2(PPh3)3] reacts with [Me 3SiC≡CPPh3]-OTf in the presence of moist [ nBu4N]F to provide the C-H activation product [RuH(C≡CPPh3)(CO)2(PPh3)2]OTf spectroscopic and structural data for which are used to assess the previously proposed analogy between phosphonioacetylide and phosphaallenylidene (cf. isonitriles) bonding descriptions in an organometallic context.

AB - [Ru(CO)2(PPh3)3] reacts with [Me 3SiC≡CPPh3]-OTf in the presence of moist [ nBu4N]F to provide the C-H activation product [RuH(C≡CPPh3)(CO)2(PPh3)2]OTf spectroscopic and structural data for which are used to assess the previously proposed analogy between phosphonioacetylide and phosphaallenylidene (cf. isonitriles) bonding descriptions in an organometallic context.

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U2 - 10.1021/om9003384

DO - 10.1021/om9003384

M3 - Article

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VL - 28

SP - 4880

EP - 4885

JO - Organometallics

JF - Organometallics

IS - 16

ER -

Reactions of [Ru(CO)₂(PPh₃)₃] with alkynylphosphonium salts: Phosphaallenylidene vs phosphonioacetylide coordination

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