Reactions of [Ru(CO)2(PPh3)3] with alkynylphosphonium salts: A phosphinoallene complex

Wee Han Ang; Richard L. Cordiner; Anthony F. Hill; Tamara L. Perry; Jörg Wagler

doi:10.1021/om900621v

Reactions of [Ru(CO)₂(PPh₃)₃] with alkynylphosphonium salts: A phosphinoallene complex

Wee Han Ang, Richard L. Cordiner, Anthony F. Hill, Tamara L. Perry, Jörg Wagler

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

[Ru(CO)₂(PPh₃)₃] reacts with either HC=CCH₂Br or [HC=CCH₂SMe₂]Br to provide the σ-allenyl complex [Ru(CH=C=CH₂)Br(CO)₂(PPh ₃)₂]; however, with [HC=CCH₂PPh₃]Br, the salt [Ru(γ²-H₂C=C=CHPPh₃)(CO) ₂(PPh₃)₂]Br is obtained, which may be described as a complex of a phosphonioallene on the basis of crystallographic data for [Ru(γ²-H₂C=C=CHPPh₃)(CO) ₂(PPh₃)₂]₂Br(PF₆) and a comparison of spectroscopic data with those for the simple allene complex [Ru(γ²-H₂C=C=CH₂)(CO) ₂(PPh₃)₂].

Original language	English
Pages (from-to)	5568-5574
Number of pages	7
Journal	Organometallics
Volume	28
Issue number	18
DOIs	https://doi.org/10.1021/om900621v
Publication status	Published - 28 Sept 2009

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@article{c4032474061648c099b26760e121dd85,

title = "Reactions of [Ru(CO)2(PPh3)3] with alkynylphosphonium salts: A phosphinoallene complex",

abstract = "[Ru(CO)2(PPh3)3] reacts with either HC=CCH2Br or [HC=CCH2SMe2]Br to provide the σ-allenyl complex [Ru(CH=C=CH2)Br(CO)2(PPh 3)2]; however, with [HC=CCH2PPh3]Br, the salt [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]Br is obtained, which may be described as a complex of a phosphonioallene on the basis of crystallographic data for [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]2Br(PF6) and a comparison of spectroscopic data with those for the simple allene complex [Ru(γ2-H2C=C=CH2)(CO) 2(PPh3)2].",

author = "Ang, \{Wee Han\} and Cordiner, \{Richard L.\} and Hill, \{Anthony F.\} and Perry, \{Tamara L.\} and J{\"o}rg Wagler",

year = "2009",

month = sep,

day = "28",

doi = "10.1021/om900621v",

language = "English",

volume = "28",

pages = "5568--5574",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "18",

}

TY - JOUR

T1 - Reactions of [Ru(CO)2(PPh3)3] with alkynylphosphonium salts

T2 - A phosphinoallene complex

AU - Ang, Wee Han

AU - Cordiner, Richard L.

AU - Hill, Anthony F.

AU - Perry, Tamara L.

AU - Wagler, Jörg

PY - 2009/9/28

Y1 - 2009/9/28

N2 - [Ru(CO)2(PPh3)3] reacts with either HC=CCH2Br or [HC=CCH2SMe2]Br to provide the σ-allenyl complex [Ru(CH=C=CH2)Br(CO)2(PPh 3)2]; however, with [HC=CCH2PPh3]Br, the salt [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]Br is obtained, which may be described as a complex of a phosphonioallene on the basis of crystallographic data for [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]2Br(PF6) and a comparison of spectroscopic data with those for the simple allene complex [Ru(γ2-H2C=C=CH2)(CO) 2(PPh3)2].

AB - [Ru(CO)2(PPh3)3] reacts with either HC=CCH2Br or [HC=CCH2SMe2]Br to provide the σ-allenyl complex [Ru(CH=C=CH2)Br(CO)2(PPh 3)2]; however, with [HC=CCH2PPh3]Br, the salt [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]Br is obtained, which may be described as a complex of a phosphonioallene on the basis of crystallographic data for [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]2Br(PF6) and a comparison of spectroscopic data with those for the simple allene complex [Ru(γ2-H2C=C=CH2)(CO) 2(PPh3)2].

UR - https://www.scopus.com/pages/publications/70349331042

U2 - 10.1021/om900621v

DO - 10.1021/om900621v

M3 - Article

SN - 0276-7333

VL - 28

SP - 5568

EP - 5574

JO - Organometallics

JF - Organometallics

IS - 18

ER -

Reactions of [Ru(CO)₂(PPh₃)₃] with alkynylphosphonium salts: A phosphinoallene complex

Abstract

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