Reactions of transition metal σ-acetylide complexes. III. Synthesis of some aryldiazovinylidene and cycloheptatrienylvinylidene complexes. X-ray structures of...

Michael I. Bruce; Christopher Dean; D. Neil Duffy; Mark G. Humphrey; George A. Koutsantonis

doi:10.1016/0022-328X(85)80329-6

Reactions of transition metal σ-acetylide complexes. III. Synthesis of some aryldiazovinylidene and cycloheptatrienylvinylidene complexes. X-ray structures of...

Michael I. Bruce^*, Christopher Dean, D. Neil Duffy, Mark G. Humphrey, George A. Koutsantonis

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

Title full: Reactions of transition metal σ-acetylide complexes. III. Synthesis of some aryldiazovinylidene and cycloheptatrienylvinylidene complexes. X-ray structures of [Ru(CCPhNNC₆H₃Me₂-3,4)(PPh₃) ₂(η-C₅H₅)][BF₄] · 0.67CH₂Cl₂ and [Ru{CCPh(C₇H₇)}(DPPE)(η-C₅H₅)][PF₆] · 0.63CH₂Cl₂. Addition of arenediazonium or tropylium salts to Ru(C₂Ph)(L)₂(η-C₅H₅) (L₂ = (PPh₃)₂ or DPPE) gives the corresponding cationic aryldiazovinylidene and cycloheptatrienylvinylidene complexes, respectively; the X-ray structures of the title complexes confirm the presence of the new ligands. The RuC and CC distances are 1.823(9) and 1.34(1) Å for the aryldiazo complex, and 1.848(9) and 1.32(1) Å for the cycloheptatrienyl derivative.

Original language	English
Pages (from-to)	c40-c44
Journal	Journal of Organometallic Chemistry
Volume	295
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(85)80329-6
Publication status	Published - 19 Nov 1985
Externally published	Yes

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@article{055d573c08554af1bc5f455acaf3cf37,

title = "Reactions of transition metal σ-acetylide complexes. III. Synthesis of some aryldiazovinylidene and cycloheptatrienylvinylidene complexes. X-ray structures of...",

abstract = "Title full: Reactions of transition metal σ-acetylide complexes. III. Synthesis of some aryldiazovinylidene and cycloheptatrienylvinylidene complexes. X-ray structures of [Ru(CCPhNNC6H3Me2-3,4)(PPh3) 2(η-C5H5)][BF4] · 0.67CH2Cl2 and [Ru{CCPh(C7H7)}(DPPE)(η-C5H 5)][PF6] · 0.63CH2Cl2. Addition of arenediazonium or tropylium salts to Ru(C2Ph)(L)2(η-C5H5) (L2 = (PPh3)2 or DPPE) gives the corresponding cationic aryldiazovinylidene and cycloheptatrienylvinylidene complexes, respectively; the X-ray structures of the title complexes confirm the presence of the new ligands. The RuC and CC distances are 1.823(9) and 1.34(1) {\AA} for the aryldiazo complex, and 1.848(9) and 1.32(1) {\AA} for the cycloheptatrienyl derivative.",

author = "Bruce, {Michael I.} and Christopher Dean and Duffy, {D. Neil} and Humphrey, {Mark G.} and Koutsantonis, {George A.}",

year = "1985",

month = nov,

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doi = "10.1016/0022-328X(85)80329-6",

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journal = "Journal of Organometallic Chemistry",

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publisher = "Elsevier B.V.",

number = "3",

}

Reactions of transition metal σ-acetylide complexes. III. Synthesis of some aryldiazovinylidene and cycloheptatrienylvinylidene complexes. X-ray structures of... / Bruce, Michael I.; Dean, Christopher; Duffy, D. Neil et al.
In: Journal of Organometallic Chemistry, Vol. 295, No. 3, 19.11.1985, p. c40-c44.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Reactions of transition metal σ-acetylide complexes. III. Synthesis of some aryldiazovinylidene and cycloheptatrienylvinylidene complexes. X-ray structures of...

AU - Bruce, Michael I.

AU - Dean, Christopher

AU - Duffy, D. Neil

AU - Humphrey, Mark G.

AU - Koutsantonis, George A.

PY - 1985/11/19

Y1 - 1985/11/19

N2 - Title full: Reactions of transition metal σ-acetylide complexes. III. Synthesis of some aryldiazovinylidene and cycloheptatrienylvinylidene complexes. X-ray structures of [Ru(CCPhNNC6H3Me2-3,4)(PPh3) 2(η-C5H5)][BF4] · 0.67CH2Cl2 and [Ru{CCPh(C7H7)}(DPPE)(η-C5H 5)][PF6] · 0.63CH2Cl2. Addition of arenediazonium or tropylium salts to Ru(C2Ph)(L)2(η-C5H5) (L2 = (PPh3)2 or DPPE) gives the corresponding cationic aryldiazovinylidene and cycloheptatrienylvinylidene complexes, respectively; the X-ray structures of the title complexes confirm the presence of the new ligands. The RuC and CC distances are 1.823(9) and 1.34(1) Å for the aryldiazo complex, and 1.848(9) and 1.32(1) Å for the cycloheptatrienyl derivative.

AB - Title full: Reactions of transition metal σ-acetylide complexes. III. Synthesis of some aryldiazovinylidene and cycloheptatrienylvinylidene complexes. X-ray structures of [Ru(CCPhNNC6H3Me2-3,4)(PPh3) 2(η-C5H5)][BF4] · 0.67CH2Cl2 and [Ru{CCPh(C7H7)}(DPPE)(η-C5H 5)][PF6] · 0.63CH2Cl2. Addition of arenediazonium or tropylium salts to Ru(C2Ph)(L)2(η-C5H5) (L2 = (PPh3)2 or DPPE) gives the corresponding cationic aryldiazovinylidene and cycloheptatrienylvinylidene complexes, respectively; the X-ray structures of the title complexes confirm the presence of the new ligands. The RuC and CC distances are 1.823(9) and 1.34(1) Å for the aryldiazo complex, and 1.848(9) and 1.32(1) Å for the cycloheptatrienyl derivative.

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Reactions of transition metal σ-acetylide complexes. III. Synthesis of some aryldiazovinylidene and cycloheptatrienylvinylidene complexes. X-ray structures of...

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