TY - JOUR
T1 - Reactions of transition metal σ-acetylide complexes. xiii
T2 - Alkylation and related reactions
AU - Bruce, Michael I.
AU - Humphrey, Mark G.
PY - 1989
Y1 - 1989
N2 - A series of 20 cationic vinylidene complexes of ruthenium and osmium [M(CCRR')(L)(L')(-C5H5)]+ (R = Me, Ph, C6H4F-4, C6F5, (CH2)2C2H; R'=Me, CH2Ph, CH2CH=CH2, CH2C≡CH, (CH2)Br; L, L' = PPh3, CNBUt, dppm, dppe; not all combinations), [(Ru(CCRCH2-)(PPh3)2(-C5H5))2]2+ and [CH2(CPhCRu(PPh3)2(-C5H5))2]2+ have been obtained from reactions between the metal acetylide complexes and the appropriate organic halides.
AB - A series of 20 cationic vinylidene complexes of ruthenium and osmium [M(CCRR')(L)(L')(-C5H5)]+ (R = Me, Ph, C6H4F-4, C6F5, (CH2)2C2H; R'=Me, CH2Ph, CH2CH=CH2, CH2C≡CH, (CH2)Br; L, L' = PPh3, CNBUt, dppm, dppe; not all combinations), [(Ru(CCRCH2-)(PPh3)2(-C5H5))2]2+ and [CH2(CPhCRu(PPh3)2(-C5H5))2]2+ have been obtained from reactions between the metal acetylide complexes and the appropriate organic halides.
UR - http://www.scopus.com/inward/record.url?scp=84970603467&partnerID=8YFLogxK
U2 - 10.1071/CH9891067
DO - 10.1071/CH9891067
M3 - Article
AN - SCOPUS:84970603467
SN - 0004-9425
VL - 42
SP - 1067
EP - 1075
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 7
ER -