Reactions of transition metal σ-acetylides. VIII. Preparation and properties of some aryldiazo-vinylidene complexes

Michael I. Bruce; Mark G. Humphrey; Michael J. Liddell

doi:10.1016/0022-328X(87)80328-5

Reactions of transition metal σ-acetylides. VIII. Preparation and properties of some aryldiazo-vinylidene complexes

Michael I. Bruce^*, Mark G. Humphrey, Michael J. Liddell

^*Corresponding author for this work

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Abstract

Fourteen aryldiazovinylidene complexes of ruthenium and osmium have been made by addition of aryldiazonium cations to the appropriate σ-acetylides. Their properties and spectra (including FAB-MS) are described, and reactions with MeOH, hydride and methoxide are reported. Addition to and protonation, alkylation, and cyclomanganation of the aryldiazo functions are also described.

Original language	English
Pages (from-to)	91-102
Number of pages	12
Journal	Journal of Organometallic Chemistry
Volume	321
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(87)80328-5
Publication status	Published - 24 Feb 1987
Externally published	Yes

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AB - Fourteen aryldiazovinylidene complexes of ruthenium and osmium have been made by addition of aryldiazonium cations to the appropriate σ-acetylides. Their properties and spectra (including FAB-MS) are described, and reactions with MeOH, hydride and methoxide are reported. Addition to and protonation, alkylation, and cyclomanganation of the aryldiazo functions are also described.

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Reactions of transition metal σ-acetylides. VIII. Preparation and properties of some aryldiazo-vinylidene complexes

Abstract

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