Reactions of transition metal acetylide complexes. IV. Synthesis and X-ray structure of a bromovinylidene complex, [Ru{CCBr(C6H4Br-4)}(PPh3)2(η-C5H5)][Br3] · CHCl3

Michael I. Bruce; Mark G. Humphrey; George A. Koutsantonis; Brian K. Nicholson

doi:10.1016/0022-328X(85)80383-1

Reactions of transition metal acetylide complexes. IV. Synthesis and X-ray structure of a bromovinylidene complex, [Ru{CCBr(C₆H₄Br-4)}(PPh₃)₂(η-C₅H₅)][Br₃] · CHCl₃

Michael I. Bruce^*, Mark G. Humphrey, George A. Koutsantonis, Brian K. Nicholson

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Halogens react with ruthenium acetylide complexes to give dark green halovinylidene derivatives. In one case, bromination of the phenyl ring of the parent phenylacetylide complex occurs, as shown by the X-ray structure of [Ru{CCBr(C₆H₄Br-4)}(PPh₃)₂(η-C₅H₅)] [Br₃] · CHCl₃. The RuC and CC distances are 1.85(1) and 1.31(2) Å, respectively.

Original language	English
Pages (from-to)	c47-c50
Journal	Journal of Organometallic Chemistry
Volume	296
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(85)80383-1
Publication status	Published - 3 Dec 1985
Externally published	Yes

Access to Document

10.1016/0022-328X(85)80383-1

Cite this

@article{85f6be1281f94515a75bff86150cf45f,

title = "Reactions of transition metal acetylide complexes. IV. Synthesis and X-ray structure of a bromovinylidene complex, [Ru{CCBr(C6H4Br-4)}(PPh3)2(η-C5H5)][Br3] · CHCl3",

abstract = "Halogens react with ruthenium acetylide complexes to give dark green halovinylidene derivatives. In one case, bromination of the phenyl ring of the parent phenylacetylide complex occurs, as shown by the X-ray structure of [Ru{CCBr(C6H4Br-4)}(PPh3)2(η-C5H5)] [Br3] · CHCl3. The RuC and CC distances are 1.85(1) and 1.31(2) {\AA}, respectively.",

author = "Bruce, {Michael I.} and Humphrey, {Mark G.} and Koutsantonis, {George A.} and Nicholson, {Brian K.}",

year = "1985",

month = dec,

day = "3",

doi = "10.1016/0022-328X(85)80383-1",

language = "English",

volume = "296",

pages = "c47--c50",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "3",

}

Reactions of transition metal acetylide complexes. IV. Synthesis and X-ray structure of a bromovinylidene complex, [Ru{CCBr(C₆H₄Br-4)}(PPh₃)₂(η-C₅H₅)][Br₃] · CHCl₃. / Bruce, Michael I.; Humphrey, Mark G.; Koutsantonis, George A. et al.
In: Journal of Organometallic Chemistry, Vol. 296, No. 3, 03.12.1985, p. c47-c50.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Reactions of transition metal acetylide complexes. IV. Synthesis and X-ray structure of a bromovinylidene complex, [Ru{CCBr(C6H4Br-4)}(PPh3)2(η-C5H5)][Br3] · CHCl3

AU - Bruce, Michael I.

AU - Humphrey, Mark G.

AU - Koutsantonis, George A.

AU - Nicholson, Brian K.

PY - 1985/12/3

Y1 - 1985/12/3

N2 - Halogens react with ruthenium acetylide complexes to give dark green halovinylidene derivatives. In one case, bromination of the phenyl ring of the parent phenylacetylide complex occurs, as shown by the X-ray structure of [Ru{CCBr(C6H4Br-4)}(PPh3)2(η-C5H5)] [Br3] · CHCl3. The RuC and CC distances are 1.85(1) and 1.31(2) Å, respectively.

AB - Halogens react with ruthenium acetylide complexes to give dark green halovinylidene derivatives. In one case, bromination of the phenyl ring of the parent phenylacetylide complex occurs, as shown by the X-ray structure of [Ru{CCBr(C6H4Br-4)}(PPh3)2(η-C5H5)] [Br3] · CHCl3. The RuC and CC distances are 1.85(1) and 1.31(2) Å, respectively.

UR - http://www.scopus.com/inward/record.url?scp=4243458522&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(85)80383-1

DO - 10.1016/0022-328X(85)80383-1

M3 - Article

AN - SCOPUS:4243458522

SN - 0022-328X

VL - 296

SP - c47-c50

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Reactions of transition metal acetylide complexes. IV. Synthesis and X-ray structure of a bromovinylidene complex, [Ru{CCBr(C₆H₄Br-4)}(PPh₃)₂(η-C₅H₅)][Br₃] · CHCl₃

Abstract

Access to Document

Other files and links

Fingerprint

Cite this