Reactions of Transition Metal s-Acetylides. V* Synthesis and X-Ray Structure of Co2 (µ-?2-PhC2Fe(CO)2(n-C5H5)) (CO)6

Michael I. Bruce; D. Neil Duffy; Mark G. Humphrey

doi:10.1071/CH9860159

Reactions of Transition Metal s-Acetylides. V* Synthesis and X-Ray Structure of Co₂ (µ-?²-PhC₂Fe(CO)₂(n-C₅H₅)) (CO)₆

Michael I. Bruce, D. Neil Duffy, Mark G. Humphrey

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The reaction between Co₂(CO)₈ and Fe(C₂Ph)(CO)₂(?-C₅H₅) gave the title complex in 44% yield. The molecular structure was determined from a single-crystal X-ray diffraction study, and consists of the transition metal acetylide acting as a conventional µ-alkyne ligand to a Co₂(CO)g unit. Crystals are monoclinic, space group P2₁/n, with a 11•610(8), b 14•657(4), c 12•526(6) Å, ß 90•30(5)°, and Z 4; 1683 independent data were refined to R 0•080, R_w 0•087.

Original language	English
Pages (from-to)	159-163
Number of pages	5
Journal	Australian Journal of Chemistry
Volume	39
Issue number	1
DOIs	https://doi.org/10.1071/CH9860159
Publication status	Published - 1985
Externally published	Yes

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title = "Reactions of Transition Metal s-Acetylides. V* Synthesis and X-Ray Structure of Co2 (µ-?2-PhC2Fe(CO)2(n-C5H5)) (CO)6",

abstract = "The reaction between Co2(CO)8 and Fe(C2Ph)(CO)2(?-C5H5) gave the title complex in 44\% yield. The molecular structure was determined from a single-crystal X-ray diffraction study, and consists of the transition metal acetylide acting as a conventional µ-alkyne ligand to a Co2(CO)g unit. Crystals are monoclinic, space group P21/n, with a 11•610(8), b 14•657(4), c 12•526(6) {\AA}, {\ss} 90•30(5)°, and Z 4; 1683 independent data were refined to R 0•080, Rw 0•087.",

author = "Bruce, \{Michael I.\} and \{Neil Duffy\}, D. and Humphrey, \{Mark G.\}",

year = "1985",

doi = "10.1071/CH9860159",

language = "English",

volume = "39",

pages = "159--163",

journal = "Australian Journal of Chemistry",

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publisher = "CSIRO",

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T1 - Reactions of Transition Metal s-Acetylides. V* Synthesis and X-Ray Structure of Co2 (µ-?2-PhC2Fe(CO)2(n-C5H5)) (CO)6

AU - Bruce, Michael I.

AU - Neil Duffy, D.

AU - Humphrey, Mark G.

PY - 1985

Y1 - 1985

N2 - The reaction between Co2(CO)8 and Fe(C2Ph)(CO)2(?-C5H5) gave the title complex in 44% yield. The molecular structure was determined from a single-crystal X-ray diffraction study, and consists of the transition metal acetylide acting as a conventional µ-alkyne ligand to a Co2(CO)g unit. Crystals are monoclinic, space group P21/n, with a 11•610(8), b 14•657(4), c 12•526(6) Å, ß 90•30(5)°, and Z 4; 1683 independent data were refined to R 0•080, Rw 0•087.

AB - The reaction between Co2(CO)8 and Fe(C2Ph)(CO)2(?-C5H5) gave the title complex in 44% yield. The molecular structure was determined from a single-crystal X-ray diffraction study, and consists of the transition metal acetylide acting as a conventional µ-alkyne ligand to a Co2(CO)g unit. Crystals are monoclinic, space group P21/n, with a 11•610(8), b 14•657(4), c 12•526(6) Å, ß 90•30(5)°, and Z 4; 1683 independent data were refined to R 0•080, Rw 0•087.

UR - https://www.scopus.com/pages/publications/84970543278

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DO - 10.1071/CH9860159

M3 - Article

AN - SCOPUS:84970543278

SN - 0004-9425

VL - 39

SP - 159

EP - 163

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 1

ER -

Reactions of Transition Metal s-Acetylides. V* Synthesis and X-Ray Structure of Co₂ (µ-?²-PhC₂Fe(CO)₂(n-C₅H₅)) (CO)₆

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