Redox flexibility in a germanium hydride manifold: hydrogen shuttling <i>via</i> oxidative addition and reductive elimination

Alexa Caise; Jamie Hicks; Andreas Heilmann; Simon Aldridge

doi:10.1039/d3cc01411h

Redox flexibility in a germanium hydride manifold: hydrogen shuttling <i>via</i> oxidative addition and reductive elimination

Alexa Caise, Jamie Hicks, Andreas Heilmann, Simon Aldridge

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

We report the synthesis of a trimetallic mixed-valence Ge(i)/Ge(ii)/Ge(iii) trihydride, which presents a structural novel motif among systems of the type (XMH)(n) (M = group 14 metal). In terms of reactivity (Ar-NiPr2)GeGe(Ar-NiPr2)(H)Ge(Ar-NiPr2)(H)(2) can act as a source of both the Ge(ii) and Ge(iv) hydrides via Ge-H reductive elimination from the central metal centre involving two different regiochemistries.

Original language	English
Pages (from-to)	7251-7254
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	47
Early online date	May 2023
DOIs	https://doi.org/10.1039/d3cc01411h
Publication status	Published - 2023
Externally published	Yes

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10.1039/d3cc01411h

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title = "Redox flexibility in a germanium hydride manifold: hydrogen shuttling via oxidative addition and reductive elimination",

abstract = "We report the synthesis of a trimetallic mixed-valence Ge(i)/Ge(ii)/Ge(iii) trihydride, which presents a structural novel motif among systems of the type (XMH)(n) (M = group 14 metal). In terms of reactivity (Ar-NiPr2)GeGe(Ar-NiPr2)(H)Ge(Ar-NiPr2)(H)(2) can act as a source of both the Ge(ii) and Ge(iv) hydrides via Ge-H reductive elimination from the central metal centre involving two different regiochemistries.",

keywords = "Tin(ii) hydride, Isomeric forms, Activation, Dihydrogen, Digermyne, Bond",

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T1 - Redox flexibility in a germanium hydride manifold

T2 - hydrogen shuttling via oxidative addition and reductive elimination

AU - Caise, Alexa

AU - Hicks, Jamie

AU - Heilmann, Andreas

AU - Aldridge, Simon

PY - 2023

Y1 - 2023

N2 - We report the synthesis of a trimetallic mixed-valence Ge(i)/Ge(ii)/Ge(iii) trihydride, which presents a structural novel motif among systems of the type (XMH)(n) (M = group 14 metal). In terms of reactivity (Ar-NiPr2)GeGe(Ar-NiPr2)(H)Ge(Ar-NiPr2)(H)(2) can act as a source of both the Ge(ii) and Ge(iv) hydrides via Ge-H reductive elimination from the central metal centre involving two different regiochemistries.

AB - We report the synthesis of a trimetallic mixed-valence Ge(i)/Ge(ii)/Ge(iii) trihydride, which presents a structural novel motif among systems of the type (XMH)(n) (M = group 14 metal). In terms of reactivity (Ar-NiPr2)GeGe(Ar-NiPr2)(H)Ge(Ar-NiPr2)(H)(2) can act as a source of both the Ge(ii) and Ge(iv) hydrides via Ge-H reductive elimination from the central metal centre involving two different regiochemistries.

KW - Tin(ii) hydride

KW - Isomeric forms

KW - Activation

KW - Dihydrogen

KW - Digermyne

KW - Bond

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Redox flexibility in a germanium hydride manifold: hydrogen shuttling <i>via</i> oxidative addition and reductive elimination

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