Resolutions of the Coulomb operator. VI. Computation of auxiliary integrals

Taweetham Limpanuparb*, Joshua W. Hollett, Peter M.W. Gill

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    11 Citations (Scopus)

    Abstract

    We discuss the efficient computation of the auxiliary integrals that arise when resolutions of two-electron operators (specifically, the Coulomb operator T. Limpanuparb, A. T. B. Gilbert, and P. M. W. Gill, J. Chem. Theory Comput. 7, 830 (2011)10.1021/ct200115t and the long-range Ewald operator T. Limpanuparb and P. M. W. Gill, J. Chem. Theory Comput. 7, 2353 (2011)10.1021/ct200305n) are employed in quantum chemical calculations. We derive a recurrence relation that facilitates the generation of auxiliary integrals for Gaussian basis functions of arbitrary angular momentum and propose a near-optimal algorithm for its use.

    Original languageEnglish
    Article number104102
    JournalJournal of Chemical Physics
    Volume136
    Issue number10
    DOIs
    Publication statusPublished - 14 Mar 2012

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