Retention of Pt→B bonding in oxidative addition reactions of the platinaboratrane [Pt(PPh3){B(mt)3}](P→B)10 (mt = methimazolyl)

Ian R. Crossley; Anthony F. Hill; Anthony C. Willis

doi:10.1021/om700835h

Retention of Pt→B bonding in oxidative addition reactions of the platinaboratrane [Pt(PPh₃){B(mt)₃}](P→B)¹⁰ (mt = methimazolyl)

Ian R. Crossley, Anthony F. Hill^*, Anthony C. Willis

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

89 Citations (Scopus)

Abstract

The platinaboratrane [Pt(PPh₃){B(mt)₃}](Pt→B) ¹⁰ (mt = methimazolyl) is prone to oxidative addition reactions with a range of substrates (Cl₂ Br₂, I₂, HCl, CH₃I) without disrupting the platinum-boron dative bond, as illustrated by the first structurally characterized platinaboratranes [PtH(PPh₃){B(mt)₃}JCl(Pt→B)⁸ and [PtI ₂{B(mt)₃}](Pt→B)⁸.

Original language	English
Pages (from-to)	312-315
Number of pages	4
Journal	Organometallics
Volume	27
Issue number	3
DOIs	https://doi.org/10.1021/om700835h
Publication status	Published - 11 Feb 2008

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title = "Retention of Pt→B bonding in oxidative addition reactions of the platinaboratrane [Pt(PPh3)\{B(mt)3\}](P→B)10 (mt = methimazolyl)",

abstract = "The platinaboratrane [Pt(PPh3)\{B(mt)3\}](Pt→B) 10 (mt = methimazolyl) is prone to oxidative addition reactions with a range of substrates (Cl2 Br2, I2, HCl, CH3I) without disrupting the platinum-boron dative bond, as illustrated by the first structurally characterized platinaboratranes [PtH(PPh3)\{B(mt)3\}JCl(Pt→B)8 and [PtI 2\{B(mt)3\}](Pt→B)8.",

author = "Crossley, \{Ian R.\} and Hill, \{Anthony F.\} and Willis, \{Anthony C.\}",

year = "2008",

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journal = "Organometallics",

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T1 - Retention of Pt→B bonding in oxidative addition reactions of the platinaboratrane [Pt(PPh3){B(mt)3}](P→B)10 (mt = methimazolyl)

AU - Crossley, Ian R.

AU - Hill, Anthony F.

AU - Willis, Anthony C.

PY - 2008/2/11

Y1 - 2008/2/11

N2 - The platinaboratrane [Pt(PPh3){B(mt)3}](Pt→B) 10 (mt = methimazolyl) is prone to oxidative addition reactions with a range of substrates (Cl2 Br2, I2, HCl, CH3I) without disrupting the platinum-boron dative bond, as illustrated by the first structurally characterized platinaboratranes [PtH(PPh3){B(mt)3}JCl(Pt→B)8 and [PtI 2{B(mt)3}](Pt→B)8.

AB - The platinaboratrane [Pt(PPh3){B(mt)3}](Pt→B) 10 (mt = methimazolyl) is prone to oxidative addition reactions with a range of substrates (Cl2 Br2, I2, HCl, CH3I) without disrupting the platinum-boron dative bond, as illustrated by the first structurally characterized platinaboratranes [PtH(PPh3){B(mt)3}JCl(Pt→B)8 and [PtI 2{B(mt)3}](Pt→B)8.

UR - https://www.scopus.com/pages/publications/39649110625

U2 - 10.1021/om700835h

DO - 10.1021/om700835h

M3 - Article

SN - 0276-7333

VL - 27

SP - 312

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JO - Organometallics

JF - Organometallics

IS - 3

ER -

Retention of Pt→B bonding in oxidative addition reactions of the platinaboratrane [Pt(PPh₃){B(mt)₃}](P→B)¹⁰ (mt = methimazolyl)

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