Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne

Lorraine M. Caldwell; Alison J. Edwards; Anthony F. Hill; Horst Neumann; Madeleine Schultz

doi:10.1021/om030040m

Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne

Lorraine M. Caldwell, Alison J. Edwards, Anthony F. Hill^*, Horst Neumann, Madeleine Schultz

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The reaction of 4,7,10-trithiatrideca-2,11-diyne with RhCl(PPh₃)₃ results in cleavage and rearrangement of the diyne with formation of the structurally characterized complex RhCl(C≡CMe)(PPh₃){κ³-S,S′,S″-S(CH= CH₂)CH₂CH₂SCH=CMeS}.

Original language	English
Pages (from-to)	2531-2534
Number of pages	4
Journal	Organometallics
Volume	22
Issue number	12
DOIs	https://doi.org/10.1021/om030040m
Publication status	Published - 9 Jun 2003

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title = "Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne",

abstract = "The reaction of 4,7,10-trithiatrideca-2,11-diyne with RhCl(PPh3)3 results in cleavage and rearrangement of the diyne with formation of the structurally characterized complex RhCl(C≡CMe)(PPh3){κ3-S,S′,S″-S(CH= CH2)CH2CH2SCH=CMeS}.",

author = "Caldwell, {Lorraine M.} and Edwards, {Alison J.} and Hill, {Anthony F.} and Horst Neumann and Madeleine Schultz",

year = "2003",

month = jun,

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doi = "10.1021/om030040m",

language = "English",

volume = "22",

pages = "2531--2534",

journal = "Organometallics",

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publisher = "American Chemical Society",

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T1 - Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne

AU - Caldwell, Lorraine M.

AU - Edwards, Alison J.

AU - Hill, Anthony F.

AU - Neumann, Horst

AU - Schultz, Madeleine

PY - 2003/6/9

Y1 - 2003/6/9

N2 - The reaction of 4,7,10-trithiatrideca-2,11-diyne with RhCl(PPh3)3 results in cleavage and rearrangement of the diyne with formation of the structurally characterized complex RhCl(C≡CMe)(PPh3){κ3-S,S′,S″-S(CH= CH2)CH2CH2SCH=CMeS}.

AB - The reaction of 4,7,10-trithiatrideca-2,11-diyne with RhCl(PPh3)3 results in cleavage and rearrangement of the diyne with formation of the structurally characterized complex RhCl(C≡CMe)(PPh3){κ3-S,S′,S″-S(CH= CH2)CH2CH2SCH=CMeS}.

UR - http://www.scopus.com/inward/record.url?scp=0037899482&partnerID=8YFLogxK

U2 - 10.1021/om030040m

DO - 10.1021/om030040m

M3 - Article

SN - 0276-7333

VL - 22

SP - 2531

EP - 2534

JO - Organometallics

JF - Organometallics

IS - 12

ER -

Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne

Abstract

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