Ring opening of organosilicon-substituted benzoxazolinone: A convenient route to chelating ureato and carbamido ligands

Jörg Wagler; Anthony F. Hill

doi:10.1021/om800796z

Ring opening of organosilicon-substituted benzoxazolinone: A convenient route to chelating ureato and carbamido ligands

Jörg Wagler^*, Anthony F. Hill

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

N-Silylated benzoxazolin-2-one reacts with N-H and C-H acidic heterocycles (benzoxazolinone, 3,5-dimethylpyrazole, N-methylimidazole) under benzoxazolinone ring cleavage and formation of ortho-siloxyphenyl-substituted ureas and carbamides, respectively. These products were shown to serve as sources for tridentate (O'NO) and (N'NO) chelating ligands.

Original language	English
Pages (from-to)	6579-6586
Number of pages	8
Journal	Organometallics
Volume	27
Issue number	24
DOIs	https://doi.org/10.1021/om800796z
Publication status	Published - 22 Dec 2008

Access to Document

10.1021/om800796z

Cite this

@article{8be09ee0d4cc433490f7460c21f5b70b,

title = "Ring opening of organosilicon-substituted benzoxazolinone: A convenient route to chelating ureato and carbamido ligands",

abstract = "N-Silylated benzoxazolin-2-one reacts with N-H and C-H acidic heterocycles (benzoxazolinone, 3,5-dimethylpyrazole, N-methylimidazole) under benzoxazolinone ring cleavage and formation of ortho-siloxyphenyl-substituted ureas and carbamides, respectively. These products were shown to serve as sources for tridentate (O'NO) and (N'NO) chelating ligands.",

author = "J{\"o}rg Wagler and Hill, {Anthony F.}",

year = "2008",

month = dec,

day = "22",

doi = "10.1021/om800796z",

language = "English",

volume = "27",

pages = "6579--6586",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "24",

}

TY - JOUR

T1 - Ring opening of organosilicon-substituted benzoxazolinone

T2 - A convenient route to chelating ureato and carbamido ligands

AU - Wagler, Jörg

AU - Hill, Anthony F.

PY - 2008/12/22

Y1 - 2008/12/22

N2 - N-Silylated benzoxazolin-2-one reacts with N-H and C-H acidic heterocycles (benzoxazolinone, 3,5-dimethylpyrazole, N-methylimidazole) under benzoxazolinone ring cleavage and formation of ortho-siloxyphenyl-substituted ureas and carbamides, respectively. These products were shown to serve as sources for tridentate (O'NO) and (N'NO) chelating ligands.

AB - N-Silylated benzoxazolin-2-one reacts with N-H and C-H acidic heterocycles (benzoxazolinone, 3,5-dimethylpyrazole, N-methylimidazole) under benzoxazolinone ring cleavage and formation of ortho-siloxyphenyl-substituted ureas and carbamides, respectively. These products were shown to serve as sources for tridentate (O'NO) and (N'NO) chelating ligands.

UR - http://www.scopus.com/inward/record.url?scp=61849171203&partnerID=8YFLogxK

U2 - 10.1021/om800796z

DO - 10.1021/om800796z

M3 - Article

SN - 0276-7333

VL - 27

SP - 6579

EP - 6586

JO - Organometallics

JF - Organometallics

IS - 24

ER -

Ring opening of organosilicon-substituted benzoxazolinone: A convenient route to chelating ureato and carbamido ligands

Abstract

Access to Document

Other files and links

Fingerprint

Cite this