Ruthenatetraboranes: Synthesis of [Ru(B3H8)(PPh3){HB(pz)3}] and Crystal Structure of [RuCl(PPh3)2{HB(pz)3}] (pz = Pyrazol-1-yl)

Nathaniel W. Alcock; Kanwaljit S. Claire; Ian D. Burns; Anthony F. Hill

doi:10.1021/ic00039a044

Ruthenatetraboranes: Synthesis of [Ru(B₃H₈)(PPh₃){HB(pz)₃}] and Crystal Structure of [RuCl(PPh₃)₂{HB(pz)₃}] (pz = Pyrazol-1-yl)

Nathaniel W. Alcock, Kanwaljit S. Claire, Ian D. Burns, Anthony F. Hill^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

89 Citations (Scopus)

Abstract

The reaction of [RuCl₂(PPh₃)₃] with K[HB(pz)₃] (pz = pyrazol-1-yl) affords [RuCl(PPh₃)₂{k³-HB(pz)₃}] [crystallographically characterized with monoclinic crystals of space group P2₁/a, Z = 8, in a unit cell of dimensions a = 19.75 (1) Å, b = 22.48 (1) Å, c = 20.283 (7) Å, and β = 112.94 (3)°], which upon treatment with NR₄[B₃H₈] (R = Me, Bu) provides the ruthenatetraborane [Ru(B₃H₈)(PPh₃){k³-HB(pz)₃}].

Original language	English
Pages (from-to)	2906-2908
Number of pages	3
Journal	Inorganic Chemistry
Volume	31
Issue number	13
DOIs	https://doi.org/10.1021/ic00039a044
Publication status	Published - 1992
Externally published	Yes

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@article{d3e362936cf44a04b423b6a202c31f07,

title = "Ruthenatetraboranes: Synthesis of [Ru(B3H8)(PPh3){HB(pz)3}] and Crystal Structure of [RuCl(PPh3)2{HB(pz)3}] (pz = Pyrazol-1-yl)",

abstract = "The reaction of [RuCl2(PPh3)3] with K[HB(pz)3] (pz = pyrazol-1-yl) affords [RuCl(PPh3)2{k3-HB(pz)3}] [crystallographically characterized with monoclinic crystals of space group P21/a, Z = 8, in a unit cell of dimensions a = 19.75 (1) {\AA}, b = 22.48 (1) {\AA}, c = 20.283 (7) {\AA}, and β = 112.94 (3)°], which upon treatment with NR4[B3H8] (R = Me, Bu) provides the ruthenatetraborane [Ru(B3H8)(PPh3){k3-HB(pz)3}].",

author = "Alcock, {Nathaniel W.} and Claire, {Kanwaljit S.} and Burns, {Ian D.} and Hill, {Anthony F.}",

year = "1992",

doi = "10.1021/ic00039a044",

language = "English",

volume = "31",

pages = "2906--2908",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - Ruthenatetraboranes

T2 - Synthesis of [Ru(B3H8)(PPh3){HB(pz)3}] and Crystal Structure of [RuCl(PPh3)2{HB(pz)3}] (pz = Pyrazol-1-yl)

AU - Alcock, Nathaniel W.

AU - Claire, Kanwaljit S.

AU - Burns, Ian D.

AU - Hill, Anthony F.

PY - 1992

Y1 - 1992

N2 - The reaction of [RuCl2(PPh3)3] with K[HB(pz)3] (pz = pyrazol-1-yl) affords [RuCl(PPh3)2{k3-HB(pz)3}] [crystallographically characterized with monoclinic crystals of space group P21/a, Z = 8, in a unit cell of dimensions a = 19.75 (1) Å, b = 22.48 (1) Å, c = 20.283 (7) Å, and β = 112.94 (3)°], which upon treatment with NR4[B3H8] (R = Me, Bu) provides the ruthenatetraborane [Ru(B3H8)(PPh3){k3-HB(pz)3}].

AB - The reaction of [RuCl2(PPh3)3] with K[HB(pz)3] (pz = pyrazol-1-yl) affords [RuCl(PPh3)2{k3-HB(pz)3}] [crystallographically characterized with monoclinic crystals of space group P21/a, Z = 8, in a unit cell of dimensions a = 19.75 (1) Å, b = 22.48 (1) Å, c = 20.283 (7) Å, and β = 112.94 (3)°], which upon treatment with NR4[B3H8] (R = Me, Bu) provides the ruthenatetraborane [Ru(B3H8)(PPh3){k3-HB(pz)3}].

UR - http://www.scopus.com/inward/record.url?scp=0001263066&partnerID=8YFLogxK

U2 - 10.1021/ic00039a044

DO - 10.1021/ic00039a044

M3 - Article

AN - SCOPUS:0001263066

SN - 0020-1669

VL - 31

SP - 2906

EP - 2908

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

ER -

Ruthenatetraboranes: Synthesis of [Ru(B₃H₈)(PPh₃){HB(pz)₃}] and Crystal Structure of [RuCl(PPh₃)₂{HB(pz)₃}] (pz = Pyrazol-1-yl)

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