Ruthenium cluster chemistry: Monodentate bis(diphenylphosphino)acetylene-ligated cluster modules in chain and dendrimer formation

Lydie Viau; Anthony C. Willis; Mark G. Humphrey

doi:10.1016/j.jorganchem.2007.01.027

Ruthenium cluster chemistry: Monodentate bis(diphenylphosphino)acetylene-ligated cluster modules in chain and dendrimer formation

Lydie Viau, Anthony C. Willis, Mark G. Humphrey^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Reaction of Ru₃(μ-dppm)(CO)₁₀ [dppm = bis(diphenylphosphino)methane] with one equivalent of dppa [dppa = bis(diphenylphosphino)acetylene] afforded Ru₃(μ-dppm)(CO)₉(η¹-dppa) which possesses a monodentate dppa ligand,an X-ray structural study revealing that all phosphorus donor atoms are arranged in equatorial coordination sites with respect to the triruthenium cluster plane.Reaction of Ru₃(CO)₉(NCMe)₃ with excess dppa afforded fair yields of Ru₃(CO)₉(η¹-dppa)₃,which possesses three monodentate dppa ligands.Reaction of three equivalents of Ru₃(μ-dppm)(CO)₉(η¹-dppa) with Ru₃(CO)₉(NCMe)₃ or reaction of Ru₃(CO)₉(η¹-dppa)₃ with excess Ru₃(μ-dppm)(CO)₁₀ afforded low yields of the dodecanuclear first-generation dendrimer Ru₃(CO)₉{PPh₂C₂PPh₂Ru₃(μ-dppm)(CO)₉}₃.Reaction of WIr₃(μ-CO)₃(CO)₈(η-C₅Me₅) with excess Ru₃(μ-dppm)(CO)₉(η¹-dppa) afforded fair yields of the decanuclear dppa-bridged tri-cluster WIr₃(CO)₉{PPh₂C₂PPh₂Ru₃(μ-dppm)(CO)₉}₂(η-C₅Me₅).

Original language	English
Pages (from-to)	2086-2091
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	692
Issue number	10
DOIs	https://doi.org/10.1016/j.jorganchem.2007.01.027
Publication status	Published - 15 Apr 2007

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@article{742c95adf3a844a8ac3b0395fb7fe76d,

title = "Ruthenium cluster chemistry: Monodentate bis(diphenylphosphino)acetylene-ligated cluster modules in chain and dendrimer formation",

abstract = "Reaction of Ru3(μ-dppm)(CO)10 [dppm = bis(diphenylphosphino)methane] with one equivalent of dppa [dppa = bis(diphenylphosphino)acetylene] afforded Ru3(μ-dppm)(CO)9(η1-dppa) which possesses a monodentate dppa ligand,an X-ray structural study revealing that all phosphorus donor atoms are arranged in equatorial coordination sites with respect to the triruthenium cluster plane.Reaction of Ru3(CO)9(NCMe)3 with excess dppa afforded fair yields of Ru3(CO)9(η1-dppa)3,which possesses three monodentate dppa ligands.Reaction of three equivalents of Ru3(μ-dppm)(CO)9(η1-dppa) with Ru3(CO)9(NCMe)3 or reaction of Ru3(CO)9(η1-dppa)3 with excess Ru3(μ-dppm)(CO)10 afforded low yields of the dodecanuclear first-generation dendrimer Ru3(CO)9{PPh2C2PPh2Ru3(μ-dppm)(CO)9}3.Reaction of WIr3(μ-CO)3(CO)8(η-C5Me5) with excess Ru3(μ-dppm)(CO)9(η1-dppa) afforded fair yields of the decanuclear dppa-bridged tri-cluster WIr3(CO)9{PPh2C2PPh2Ru3(μ-dppm)(CO)9}2(η-C5Me5).",

keywords = "Crystal structure, Dendrimer, Iridium, Ruthenium, Tungsten",

author = "Lydie Viau and Willis, {Anthony C.} and Humphrey, {Mark G.}",

year = "2007",

month = apr,

day = "15",

doi = "10.1016/j.jorganchem.2007.01.027",

language = "English",

volume = "692",

pages = "2086--2091",

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issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "10",

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TY - JOUR

T1 - Ruthenium cluster chemistry

T2 - Monodentate bis(diphenylphosphino)acetylene-ligated cluster modules in chain and dendrimer formation

AU - Viau, Lydie

AU - Willis, Anthony C.

AU - Humphrey, Mark G.

PY - 2007/4/15

Y1 - 2007/4/15

N2 - Reaction of Ru3(μ-dppm)(CO)10 [dppm = bis(diphenylphosphino)methane] with one equivalent of dppa [dppa = bis(diphenylphosphino)acetylene] afforded Ru3(μ-dppm)(CO)9(η1-dppa) which possesses a monodentate dppa ligand,an X-ray structural study revealing that all phosphorus donor atoms are arranged in equatorial coordination sites with respect to the triruthenium cluster plane.Reaction of Ru3(CO)9(NCMe)3 with excess dppa afforded fair yields of Ru3(CO)9(η1-dppa)3,which possesses three monodentate dppa ligands.Reaction of three equivalents of Ru3(μ-dppm)(CO)9(η1-dppa) with Ru3(CO)9(NCMe)3 or reaction of Ru3(CO)9(η1-dppa)3 with excess Ru3(μ-dppm)(CO)10 afforded low yields of the dodecanuclear first-generation dendrimer Ru3(CO)9{PPh2C2PPh2Ru3(μ-dppm)(CO)9}3.Reaction of WIr3(μ-CO)3(CO)8(η-C5Me5) with excess Ru3(μ-dppm)(CO)9(η1-dppa) afforded fair yields of the decanuclear dppa-bridged tri-cluster WIr3(CO)9{PPh2C2PPh2Ru3(μ-dppm)(CO)9}2(η-C5Me5).

AB - Reaction of Ru3(μ-dppm)(CO)10 [dppm = bis(diphenylphosphino)methane] with one equivalent of dppa [dppa = bis(diphenylphosphino)acetylene] afforded Ru3(μ-dppm)(CO)9(η1-dppa) which possesses a monodentate dppa ligand,an X-ray structural study revealing that all phosphorus donor atoms are arranged in equatorial coordination sites with respect to the triruthenium cluster plane.Reaction of Ru3(CO)9(NCMe)3 with excess dppa afforded fair yields of Ru3(CO)9(η1-dppa)3,which possesses three monodentate dppa ligands.Reaction of three equivalents of Ru3(μ-dppm)(CO)9(η1-dppa) with Ru3(CO)9(NCMe)3 or reaction of Ru3(CO)9(η1-dppa)3 with excess Ru3(μ-dppm)(CO)10 afforded low yields of the dodecanuclear first-generation dendrimer Ru3(CO)9{PPh2C2PPh2Ru3(μ-dppm)(CO)9}3.Reaction of WIr3(μ-CO)3(CO)8(η-C5Me5) with excess Ru3(μ-dppm)(CO)9(η1-dppa) afforded fair yields of the decanuclear dppa-bridged tri-cluster WIr3(CO)9{PPh2C2PPh2Ru3(μ-dppm)(CO)9}2(η-C5Me5).

KW - Crystal structure

KW - Dendrimer

KW - Iridium

KW - Ruthenium

KW - Tungsten

UR - http://www.scopus.com/inward/record.url?scp=33947605762&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2007.01.027

DO - 10.1016/j.jorganchem.2007.01.027

M3 - Article

SN - 0022-328X

VL - 692

SP - 2086

EP - 2091

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 10

ER -

Ruthenium cluster chemistry: Monodentate bis(diphenylphosphino)acetylene-ligated cluster modules in chain and dendrimer formation

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