Semi-bridging σ-silyls as Z-type ligands

Benjamin J. Frogley, Anthony F. Hill*, Manab Sharma, Arup Sinha, Jas S. Ward

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    6 Citations (Scopus)


    The reactions of SiHPh(NCH2PPh2)2C6H4-1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M2{μ-κ3-Si,P,P′-SiPh(CH2PPh2)2C6H4}2] (M = Ni, Pd, Pt) in which the M-M bond is unsymmetrically bridged by two σ-silyl groups. The asymmetry of the M2Si2 core increases from Ni through Pd to Pt and is consistent with a bonding description in which one metal acts as an electron pair donor to a trigonal bipyramidal 'Z-type' silicon centre, reminsicent of semi-bridging coordination by CO, carbynes and boryl ligands.

    Original languageEnglish
    Pages (from-to)3532-3535
    Number of pages4
    JournalChemical Communications
    Issue number24
    Publication statusPublished - 25 Mar 2020


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